When light interacts with matter by means of scattering and absorption, we observe the resulting color. Light also probes the symmetry of matter and the result is encoded in its polarization. In the special case of circularly-polarized light, which is especially relevant in nonlinear optics, quantum photonics, and physical chemistry, a critical dimension of symmetry is along the longitudinal direction. We examine recent advances in controlling circularly-polarized light and reveal that the commonality in these advances is in judicious control of longitudinal symmetry. In particular, in the use of high quality-factor modes in dielectric metasurfaces, the finite thickness can be used to tune the modal profile. These symmetry considerations can be applied in multiplexed optical communication schemes, deterministic control of quantum emitters, and sensitive detection of the asymmetry of small molecules.
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http://dx.doi.org/10.1515/nanoph-2023-0175 | DOI Listing |
Materials (Basel)
January 2025
College of Chemistry, Sichuan University, Chengdu 610064, China.
Circularly polarized luminescence (CPL) is an emerging field with significant applications in molecular electronics, optical materials, and chiroptical sensing. Achieving efficient CPL emission in organic systems remains a major challenge, particularly in the development of materials with high fluorescence quantum yields (Φ) and large luminescence dissymmetry factors (g). Herein, we report the efficient synthesis of shape-persistent tetraphenylethylene macrocycles and investigate its potential as a CPL material.
View Article and Find Full Text PDFMolecules
December 2024
School of Physics and Optoelectronics Engineering, Ludong University, Yantai 264005, China.
The substituent effect has a significant influence on the optical properties of spectral shape, width, and wavelength, and the intensities of the maximum peaks of emission (EMI) and circularly polarized luminescence (CPL). In this work, we conducted a systematic theoretical study to investigate how substituents alter the optical response in the EMI and CPL spectra of three [7]helicene derivatives at the vibronic level. To incorporate the vibronic effect, a state-of-the-art time-dependent (TD) method was used to achieve the fully converged spectra.
View Article and Find Full Text PDFACS Nano
January 2025
Jiangsu Key Laboratory of Frontier Material Physics and Devices, School of Physical Science and Technology, Soochow University, Suzhou, Jiangsu 215006, China.
Circular differential scattering (CDS) spectroscopy has been developed as a powerful method for the characterization of the optical activity of individual plasmonic nanostructures and their complexes with chiral molecules. However, standard measurement setups often result in artifacts that have long raised concerns on the interpretation of spectral data. In fact, the detection limit of CDS setups is constrained by the high level of artifacts, to ±10%.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics, The University of Tokyo, Bunkyo, Tokyo 113-0033, Japan.
We have found that surface superstructures made of "monolayer alloys" of Tl and Pb on Si(111), having giant Rashba effect, produce nonreciprocal spin-polarized photocurrent via circular photogalvanic effect (CPGE) by obliquely shining circularly polarized near-infrared (IR) light. CPGE is here caused by the injection of in-plane spin into spin-split surface-state bands, which is observed only on Tl-Pb alloy layers but not on single-element Tl nor Pb layers. In the Tl-Pb monolayer alloys, despite their monatomic thickness, the magnitude of CPGE is comparable to or even larger than the cases of many other spin-split thin-film materials.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Zhengzhou University, College of Chemistry, No 100. Kexue Avenue, 450001, Zhengzhou, CHINA.
Chiral metal organic cage compounds with excellent circularly polarized luminescent performance have broad application prospects in many fields. Herein, two lanthanide complexes with luminescent properties in the form of racemic hexagonal octahedral cages were synthesized using a tri (β-diketone) ligand. Eu6(C21H6F15O6)8(H2O)6 exhibited red light emission with high quantum yields of 61%.
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