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Simple divalent metal salts as robust and efficient initiators for the ring-opening polymerisation of -lactide. | LitMetric
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Simple divalent metal salts as robust and efficient initiators for the ring-opening polymerisation of -lactide.

Phoebe A Lowy Jennifer A Garden

RSC Adv

EaStCHEM School of Chemistry, University of Edinburgh Edinburgh EH9 3FJ UK

Published: November 2024

Simple divalent metal benzoxides are reported as robust and efficient catalysts for lactide (LA) polymerisation. Following a "pre-stir" step to aid solubility, the best performing catalyst, Zn(OBn), gave quantitative monomer conversion in just 30 seconds and performed well under industrially relevant settings with high monomer loadings, bulk polymerisation conditions and non-anhydrous conditions using technical grade LA.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11605502PMC
http://dx.doi.org/10.1039/d4ra07747dDOI Listing

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