In this study, a petal-like ternary metal-layered double hydroxide (FeCoLa-LDH) was synthesized through a facile one-step hydrothermal method and in situ grown on carbon felt (CF). The FeCoLa-LDH/CF composite electrode was applied in a heterogeneous electro-Fenton (HEF) system for the degradation of moxifloxacin hydrochloride (MOX). Characterization revealed that La-doped FeCo-LDH/CF exhibited petal-like layered structure rather than particle's structure, with higher surface defect degree and an increased electroactive surface area (ESA) compared to FeCo-LDH/CF. The composite electrode effectively degraded MOX across a pH range of 3-9. Under optimal conditions, it achieved a degradation efficiency of 92.2% within 45 min and 96.8% within 120 min. After 120 min, 82.4% of the chemical oxygen demand (COD) was removed. The superior degradation performance was primarily attributed to La doping, which enhanced electron transfer between Co/Co and Fe/Fe, promoting in situ HO generation and causing rapid conversion of HO to hydroxyl radical(•OH) on the electrode surface. Radical quenching experiments confirmed that •OH was the primary reactive species. The possible MOX degradation pathways were elucidated through liquid chromatography-mass spectrometry (LC-MS) analysis and density functional theory (DFT) calculations, and a catalytic mechanism of HEF process was proposed. Moreover, the electrode maintained 82.8% efficiency after five cycles, with lower ion leaching and broader pollutant applicability. Moreover, good degradation efficiencies of MOX were still observed in actual water bodies. Toxicity tests confirmed that MOX degradation intermediate products had low plant toxicity. This study provides a promising high-performance cathode for antibiotic removal from wastewater.
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http://dx.doi.org/10.1016/j.chemosphere.2024.143845 | DOI Listing |
ACS Nano
December 2024
Department of Materials Science and Engineering, National University of Singapore, Singapore117575, Singapore.
A Rashba spin-splitting state with spin-momentum locking enables the charge-spin interconversion known as the Rashba effect, induced by the interplay of inversion symmetry breaking (ISB) and spin-orbit coupling (SOC). Enhancing spin-splitting strength is promising to achieve high spin-orbit torque (SOT) efficiency for low-power-consumption spintronic devices. However, the energy scale of natural ISB at the interface is relatively small, leading to the weak Rashba effect.
View Article and Find Full Text PDFSmall
December 2024
School of Electrical, Computer and Energy Engineering, Arizona State University, Tempe, AZ, 85281, USA.
Electrochemical capacitors (ECs) offer superior specific capacitance for energy storage compared to traditional electrolytic capacitors but face limitations in alternating current (AC) filtering due to the need for balancing fast response and high capacitance. This study addresses these challenges by developing a freestanding nanostructured carbon electrode, derived from the rapid carbonization of bacterial cellulose (BC) embedded with zeolitic imidazolate framework 8 (ZIF-8) and in situ formed carbon nanotubes (CNTs). The electrode exhibits an exceptionally low area resistance of 9.
View Article and Find Full Text PDFEnviron Res
December 2024
State Key Lab of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, 610500, PR China; College of Petroleum and Gas Engineering Southwest Petroleum University, Chengdu, 610500, PR China; Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, Chengdu, 610500, PR China. Electronic address:
Adjusting the structure of the membrane and improving its performance proved to be an effective technique for accomplishing efficient dye wastewater purification. Water erosion of polyvinylpyrrolidone (PVP) core in polyacrylonitrile (PAN) nanofiber membrane modified with UiO-66-NH was successfully achieved, in this study, using coaxial electrospinning, and ZIF-8 with excellent performance was further epitaxy-grown in situ. Two differently shaped and positively charged MOFs confer strong adsorption capacity (adsorption capacity >2042 mg/g) on cationic dyes.
View Article and Find Full Text PDFPlant Methods
December 2024
Department of Soil and Crop Sciences, Texas A&M University and Texas A&M AgriLife Research, College Station, TX, USA.
Background: Nitrate (NO) is one of the two major forms of inorganic nitrogen absorbed by plant roots, and the tissue nitrate concentration in roots is considered important for optimizing developmental programs. Technologies to quantify the expression levels of nitrate transporters and assimilating enzymes at the cellular level have improved drastically in the past decade. However, a technological gap remains for detecting nitrate at a high spatial resolution.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
College of Materials Science and Engineering, State Key Laboratory of Bio-Fiber and Eco-textiles, Collaborative Innovation Center for Marine Biobased Fibers and Ecological textile technology Institute of Marine Biobased Materials, Qingdao University, Qingdao 266071, P. R. China.
Mimicking natural organisms to directly fabricate multiresponsive structural color patterns from small molecules is of great significance for information encryption but remains challenging. Herein, we present a bionic entanglement-interlocking microphase separation strategy for in situ growth of multiresponsive structural color patterns within hydrogel matrixes. The precursor solutions of common polymerization-induced phase-separated materials are used as small-molecule nutrients.
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