Research on the use of organic materials as soil amendments for the remediation of Cd-contaminated agricultural land exists. However, the mechanisms based on which organic materials affect the distribution and availability of Cd in soil aggregates remain unclear. Here, Cd-contaminated paddy soil and different bio-based materials were used for rice pot experiments. Rhizosphere soils were separated into six particle sizes. Cd fractions were analyzed with BCR sequential extraction and specific functional groups associated with Cd were characterized using XPS. We found that bio-based materials promoted the formation of large aggregates to different extents. Cd tended to be enriched in fine- and coarse-grained soil particles, which is mainly related to the soil organic matter. Bio-based materials reduced the relative content of the weak-acid extractable fraction and increased the relative content of the reducible fraction, resulting in soil Cd immobilization. Soil dissolved organic matter (DOM) was the key factor affecting the distribution and availability of Cd in soil aggregates and different organic matter and Cd-binding functional groups in aggregates altered the Cd availability in soil. The results provide insight and guidance for understanding the cadmium immobilization mechanism and screening appropriate materials in the remediation of agricultural land.
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http://dx.doi.org/10.1016/j.scitotenv.2024.177739 | DOI Listing |
Int J Biol Macromol
December 2024
College of Textile Science and Engineering (International Institute of Silk Institute), Zhejiang Sci-Tech University, Hangzhou 310018, China. Electronic address:
Developing eco-friendly and effective flame retardants is crucial for enhancing the fire resistance of polymeric materials. This study developed a novel nitrogen‑phosphorus (NP) synergistic nanocellulose-based flame retardant (CNC-PEI-PA) by grafting polyethyleneimine (PEI) and phytic acid (PA) onto the CNC. CNC-PEI-PA demonstrated remarkable thermal stability, char-forming ability, and antibacterial activity.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
School of Mechanical Engineering, School of Food and Biological Engineering, Chengdu University, Chengdu City 610106, China. Electronic address:
Chitosan is a bio-based material that is more environmentally friendly than traditional petroleum-based materials, but its biofilms often suffer from brittleness and limited antioxidant and antibacterial properties. To overcome these challenges, chemically modified chitosan is a key solution. Herein, a novel CS-LA/CHA films were prepared through a radical reaction of chitosan (CS), lipoic acid/chalcone derivative (LA/CHA) and N,N-methylene bisacrylamide (MBA).
View Article and Find Full Text PDFSci China Life Sci
December 2024
Tianjin Institute of Industrial Biotechnology, Chinese Academy of Sciences, Tianjin, 300308, China.
Lignin, an energy-rich and adaptable polymer comprising phenylpropanoid monomers utilized by plants for structural reinforcement, water conveyance, and defense mechanisms, ranks as the planet's second most prevalent biopolymer, after cellulose. Despite its prevalence, lignin is frequently underused in the process of converting biomass into fuels and chemicals. Instead, it is commonly incinerated for industrial heat due to its intricate composition and resistance to decomposition, presenting obstacles for targeted valorization.
View Article and Find Full Text PDFMacromol Rapid Commun
December 2024
Paris-Est Creteil University, CNRS, ICMPE, UMR 7182, Thiais, 94320, France.
The design of a new visible-light methacrylated-based kraft lignin photosensitizer (MAcL) of iodonium salt (Iod) for the free-radical polymerization (FRP) of polyethylene glycol dimethacrylate (PEGDMA) under LEDs@405, 455, 470, 505, and 530 nm is reported. As demonstrated by laser flash photolysis (LFP) and electron paramagnetic resonance spin-trapping (EPR ST) experiments, the combination of MAcL with an electron acceptor (Iod) and trimethylolpropane tris(3-mercaptopropionate) (TT) used as a crosslinker, leads to the formation of highly efficient initiating radicals, i.e.
View Article and Find Full Text PDFJ Mater Chem B
December 2024
Key Laboratory of Bio-based Polymeric Materials Technology and Application of Zhejiang Province, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 1219 Zhongguan West Road, Zhenhai, Ningbo, Zhejiang, 315201, China.
Recent advances in medical plastics highlight the need for sustainable materials with desirable elastic properties. Traditional polyester elastomers have been used as alternatives to polyvinyl chloride (PVC) due to their biocompatibility and adjustable mechanical properties. However, these materials often lack the necessary stability and toughness for reliable medical applications.
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