The development of defect-free flint glass for use in telescopes and navigational instruments was a key technological challenge facing European chemists, natural philosophers, and artisans that emerged in the 1750s. In 1805, Pierre-Louis Guinand, a Swiss artisan, invented a fireclay stirrer used to stir molten flint glass to create a homogenous mixture relatively free of defects. In this paper, I show it was not Guinand, but French chemist Antoine Baumé, who first came up with the idea of using a fireclay stirrer. More important, both Guinand and another early optical glass researcher, Josiah Wedgwood, knew of and were influenced by Baumé's work. Baumé's optical glass contributions have been forgotten over the years for several reasons. First, he never promoted his idea of a fireclay stirrer due to the limited support and likelihood of failure for such an artisanal-focused project within the , which stressed theory over practice with regards to glassmaking. Second, glassmakers were hesitant to reveal their trade secrets and sources. And third, until fairly recently, Baumé's unrelenting support of the phlogiston theory led to his relegation as a minor figure in the history of chemistry, and his optical glass ideas fell off the radar of subsequent historians.
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http://dx.doi.org/10.1080/00026980.2024.2419312 | DOI Listing |
Nanomicro Lett
December 2024
Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, People's Republic of China.
Dual-band electrochromic devices capable of the spectral-selective modulation of visible (VIS) light and near-infrared (NIR) can notably reduce the energy consumption of buildings and improve the occupants' visual and thermal comfort. However, the low optical modulation and poor durability of these devices severely limit its practical applications. Herein, we demonstrate an efficient and flexible bifunctional dual-band electrochromic device which not only shows excellent spectral-selective electrochromic performance with a high optical modulation and a long cycle life, but also displays a high capacitance and a high energy recycling efficiency of 51.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices, Huizhou University, Huizhou 516007, China.
W-doped ZnO (WZO) films were deposited on glass substrates by using RF magnetron sputtering at different substrate bias voltages, and the relationships between microstructure and optical and electrical properties were investigated. The results revealed that the deposition rate of WZO films first decreased from 8.8 to 7.
View Article and Find Full Text PDFBiosensors (Basel)
December 2024
Department of Biochemistry and Chemistry, La Trobe University, Bundoora, VIC 3086, Australia.
Surface-enhanced Raman scattering (SERS) is a powerful optical sensing platform that amplifies the target signals by Raman scattering. Despite SERS enabling a meager detection limit, even at the single-molecule level, SERS also tends to equally enhance unwanted molecules due to the non-specific binding of noise molecules in clinical samples, which complicates its use in complex samples such as bodily fluids, environmental water, or food matrices. To address this, we developed a novel non-fouling biomimetic SERS sensor by self-assembling an anti-adhesive, anti-fouling, and size-selective Lubricin (LUB) coating on gold nanoparticle (AuNP) functionalized glass slide surfaces via a simple drop-casting method.
View Article and Find Full Text PDFBMJ Open
December 2024
School of Medicine, Dentistry and Biomedical Sciences, Centre for Public Health, Queen's University Belfast MDBS, Belfast, UK
Introduction: Presbyopia, difficulty in seeing close-ups, affects a billion people globally. Mobile financial services (MFS) have been mandated since January 2021 for Bangladesh government social safety net payments, including old age allowance (OAA) and widow allowance (WA). We report the protocol for the Transforming Households with Refraction and Innovative Financial Technology randomised trial assessing the impact on the use of online banking of providing presbyopic safety net beneficiaries with reading glasses, and brief smartphone and mobile banking app training.
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