Velocity-map imaging (VMI) is a key tool for studying outgoing electrons or ions following optical strong-field interactions of atoms and molecules and provides good momentum resolution even if the source volume of the fragments extends along a laser beam path. Here, we demonstrate within an enhancement cavity how, independently of the focal Rayleigh length, counter-propagating pulses longitudinally compress the ionization volume down to few tens of micrometers. We observe nonlinear above-threshold ionization (ATI) processes confined to the spatial overlap of femtosecond pulses, whereas the shortened ionization volume makes an electrostatic lens unnecessary for VMI.
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http://dx.doi.org/10.1364/OL.540612 | DOI Listing |
J Phys Chem A
December 2024
Department of Chemistry, KAIST, Daejeon 34141, Republic of Korea.
A photodetachment and photoelectron spectroscopic study by employing a cryogenically cooled ion trap combined with a velocity-map imaging setup has been carried out to unravel the vibrational structures and autodetachment dynamics of the dipole-bound states (DBSs) of -, -, and -methylphenolate anions (-, -, and -CHPhO). The electron binding energy of the DBS increases monotonically with the increase of the neutral dipole moment to give respective values of 66 ± 15, 123 ± 18, or 154 ± 14 cm for the -, -, or -isomer. The different electron-donating effects of the methyl moieties in the three geometrically different isomers seem to be reflected in the experiment.
View Article and Find Full Text PDFMed Phys
December 2024
Department of Electronics and Electrical Engineering, Indian Institute of Technology Guwahati, Assam, India.
Background: Measurement noise often leads to inaccurate shear wave phase velocity estimation in ultrasound shear wave elastography. Filtering techniques are commonly used for denoising the shear wavefields. However, these filters are often not sufficient, especially in fatty tissues where the signal-to-noise ratio (SNR) can be very low.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
School of Physics and Optoelectronic Engineering, Yangtze University, Jingzhou 434023, China.
We obtained the photoelectron spectra of Rh(CN) using the negative ion photoelectron velocity-map imaging (NI-PEVMI) technique and revealed the photodesorption process of Rh(CN). The vertical detachment energy (VDE) and adiabatic detachment energy (ADE) of Rh(CN) have both been experimentally reported to be 2.04 (3) eV.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
School of Geographical Sciences, Shanxi Normal University, No. 339, Taiyu Road, Taiyuan, Shanxi 030031, People's Republic of China.
The conjugate-pair molecules of CO and CPt provide a prototype of the autogenic isolobal relationship between the O and Pt atoms that can rationalize the structure and reactivity trends of platinum carbides. Herein, the photoelectron detachment at 532 nm has been recorded for the gas-phase CPt by using the photoelectron velocity-map imaging spectroscopy. The vibrationally resolved ground-state transition reveals a wealth of information concerning the electronic ground states of CPt.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
Radboud University Nijmegen, Institute for Molecules and Materials, Heijendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.
In molecular beam scattering experiments, an important technique for measuring product energy and angular distributions is velocity map imaging following photoionization of one or more scattered species. For studies with cold molecular beams, the ultimate resolution of such a study is often limited by the product detection process. When state-selective ionization detection is used, excess energy from the ionization step can transfer to kinetic energy in the target molecular ion-electron pair, resulting in measurable cation recoil.
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