This research introduces a new way to create a composite material (PLA/EG) for 3D printing. It combines polylactic acid (PLA) with exfoliated graphite (EG) using a physical mixing method, followed by direct mixing in a single-screw extruder. Structural and vibrational analyses using X-ray diffraction and Fourier transform infrared spectroscopy confirmed the PLA/EG's formation (composite). The analysis also suggests physical adsorption as the primary interaction between the two materials. The exfoliated graphite acts as a barrier (thermal behavior), reducing heat transfer via TG. Electrochemical measurements reveal redox activity (cyclic voltammetry) with a specific capacitance of ~ 6 F g, low solution resistance, and negligible charge transfer resistance, indicating ion movement through a Warburg diffusion process. Additionally, in terms of complex behavior (electrochemical impedance spectroscopy), the PLA/EG's actual capacitance C'(ω) displayed a value greater than 1000 μF cm, highlighting the composite's effectiveness in storing charge. These results demonstrate that PLA/EG composites hold significant promise as electrodes in electronic devices. The methodology used in this study not only provides a practical way to create functional composites but also opens doors for new applications in electronics and energy storage.
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http://dx.doi.org/10.3390/polym16223131 | DOI Listing |
J Am Chem Soc
January 2025
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Although microenvironments surrounding single-atom catalysts (SACs) have been widely demonstrated to have a remarkable effect on their catalytic performances, it remains unclear whether the local structure beyond the secondary coordination shells works as well or not. Herein, we employed a series of metal-organic frameworks (MOFs) with well-defined and tunable second-beyond coordination spheres as model SAC electrocatalysts to discuss the influence of long-distance structure on the ammonia synthesis from nitrate, which were synthesized and denoted as Cu-NDI-X (X = NMe, H, F). It is first experimentally confirmed that the remote substitution of function groups beyond the secondary coordination sphere can remarkably affect the activity of ammonia synthesis.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Nanjing University of Aeronautics and Astronautics, College of Materials Science and Technology, No. 169 Sheng Tai West Road, Jiangning District, Nanjing, Jiangsu, China, 211106, Nanjing, CHINA.
The neutral oxygen catalysis is an electrochemical reaction of the utmost importance in energy generation, storage application, and chemical synthesis. However, the restricted availability of protons poses a challenge to achieving kinetically favorable oxygen catalytic reactions. Here, we alter the interfacial water orientation by adjusting the Brønsted acidity at the catalyst surface, to break the proton transfer limitation of neutral oxygen electrocatalysis.
View Article and Find Full Text PDFAdv Mater
January 2025
Center of Energy Storage Materials and Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid-State Microstructures and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, 210093, P. R. China.
The energy density of layered oxides of Li-ion batteries can be enhanced by inducing oxygen redox through replacing transition metal (TM) ions with Li ions in the TM layer. Undesirably, the cathodes always suffer from unfavorable structural degradation, which is closely associated with irreversible TM migration and slab gliding, resulting in continuous capacity and voltage decay. Herein, attention is paid to the Li ions in the TM layer (Li) and find their extra effects beyond inducing oxygen redox, which has been rarely mentioned.
View Article and Find Full Text PDFSmall
January 2025
College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065, China.
Solar desalination shows promise in tackling freshwater shortages, but challenges arise from the trade-off between water transportation and heat supply, affecting evaporators' efficiency and salt resistance. Additionally, intermittent nature of solar radiation significantly diminishes overall evaporative performance. This study presents dual-gradient heating solar evaporator for efficient desalination.
View Article and Find Full Text PDFData Brief
February 2025
School of Engineering and Technology, University of New South Wales, Canberra, Australia.
This dataset is generated from real-time simulations conducted in MATLAB/Simscape, focusing on the impact of smart noise signals on battery energy storage systems (BESS). Using Deep Reinforcement Learning (DRL) agent known as Proximal Policy Optimization (PPO), noise signals in the form of subtle millivolt and milliampere variations are strategically created to represent realistic cases of False Data Injection Attacks (FDIA). These signals are designed to disrupt the State of Charge (SoC) and State of Health (SoH) estimation blocks within Unscented Kalman Filters (UKF).
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