BiTe/Carbon Nanotube Hybrid Nanomaterials as Catalysts for Thermoelectric Hydrogen Peroxide Generation.

Molecules

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212000, China.

Published: November 2024

Harnessing waste heat from environmental or industrial sources presents a promising approach to eco-friendly and sustainable chemical synthesis. In this study, we introduce a thermoelectrocatalytic (TECatal) system capable of utilizing even small amounts of heat for hydrogen peroxide (HO) production. We developed a nanohybrid structure, combining carbon nanotubes (CNTs) and BiTe nanoflakes (BiTe/CNTs), through a one-pot synthesis method. BiTe, as a thermoelectric (TE) material, generates charge carriers under a temperature gradient via the Seebeck effect, enabling them to participate in surface redox reactions. However, the rapid recombination of these charge carriers greatly limits the TECatal activity. In the BiTe/CNTs nanohybrid system, the introduction of CNTs substantially enhances the efficiency of HO production, as the strong bonding between CNTs and BiTe, along with the excellent conductivity of CNTs, facilitates charge carrier separation and transport, as confirmed by TE electrochemical tests. This study underscores the significant potential of thermoelectric nanomaterials for converting waste heat into green chemical synthesis.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11596737PMC
http://dx.doi.org/10.3390/molecules29225242DOI Listing

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