Assessment of pesticide contamination in hill reservoirs: combination of a rainfed farming survey and water multiresidue monitoring (Lebna watershed, Cap Bon, Tunisia).

Due to Mediterranean climatic conditions, traditional pluvial agrosystems are widespread along the southern Mediterranean shore and were previously thought to have minimal impact on surface water resources due to low agricultural input levels. However, current pesticide applications are now considered to contribute significantly to the contamination of surface water resources, which may result in severe impacts on biodiversity and the environment. This study examined the presence and mobility risk of pesticides in the surface waters of the Lebna watershed in northeastern Tunisia, a rainfed Mediterranean agricultural region. Water samples were collected from eight hilly reservoirs and the Lebna dam over three farming seasons (2017-2018, 2019-2020, and 2020-2021) and analyzed for 469 pesticide active ingredients (PAIs). According to the field questionnaire, local farmers used 44 PAIs, including 15 herbicides, 21 fungicides, and 8 insecticides. Seventeen pesticide molecules were detected, with glyphosate (1.73 µg L) and 2,4-D (0.23 µg L) being the most prevalent. Despite toxicity indexes, which classify a threat of pesticides as low to moderate, their concentrations may now exceed European standards for drinking water and endanger aquatic life. According to the Pesticide Impact Rating Index (PIRI), PAIs can be organized into three mobility risk categories: medium to high for 2,4-D and glyphosate, low for five PAIs, and very low for 13 undetected PAIs. This work provides the first assessment of pesticide contamination in surface waters of the Cap Bon region, raising concerns about water quality in a low-input agrochemical system and increasing interest in similar contexts.