We introduce phonon state tomography (PST) as a diagnostic probe of electron dynamics in solids whose phonons are optically excited by a laser pulse at initial time. Using a projected-purified matrix-product states algorithm, PST decomposes the exact correlated electron-phonon wavefunction into contributions from purely electronic states corresponding to statistically typical configurations of the optically accessible phononic response, enabling a "tomographic" reconstruction of the electronic dynamics generated by the phonons. Thus, PST may be used to diagnose electronic behavior in experiments that access only the phonon response, such as thermal diffuse X-ray and electron scattering. We study the dynamics of a metal whose infrared phonons are excited by an optical pulse at initial time and use it to simulate the sample-averaged momentum-resolved phonon occupancy and accurately reconstruct the electronic correlations. We also use PST to analyze the influence of different pulse shapes on the light-induced enhancement and suppression of electronic correlations.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/acs.nanolett.4c04314 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Beijing University of Chemical Technology, State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, 100190, Beijing, CHINA.
Oligomerized electron acceptors, featuring molecular weights akin to polymers and well-defined chemical structures, have emerged as promising candidates for organic solar cells (OSCs) due to their consistent batch-to-batch reproducibility and improved thermal stability. In this study, we developed a series of oligomerized electron acceptors incorporating alkynyl linkages via an efficient Sonogashira coupling reaction between alkyne-substituted Y-type precursors and multi-substituted iodobenzenes. This method produced monomeric (S-Alkyne-YF), dimeric (D-Alkyne-YF), and trimeric (T-Alkyne-YF) configurations, enabling systematic control over molecular size and substituent arms.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Chemistry and Physics, ARC Research Hub in Zero-emission Power Generation for Carbon Neutrality, and Centre for Materials Science, Queensland University of Technology, Brisbane, Queensland, 4000, Australia.
SnTe-based thermoelectric materials have attracted significant attention for their exceptional performance in mid-to-high temperature ranges, positioning them as promising candidates for thermoelectric power generation. However, their efficiency is constrained by challenges related to electronic structure, defect chemistry, and phonon behavior. This review comprehensively summarizes advancements in SnTe thermoelectric materials and devices over the past five years, focusing on strategies to address these limitations.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.
Understanding charge transport in semiconductor quantum dot (QD) assemblies is important for developing the next generation of solar cells and light-harvesting devices based on QD technology. One of the key factors that governs the transport in such systems is related to the hybridization between the QDs. Recent experiments have successfully synthesized QD molecules, arrays, and assemblies by directly fusing the QDs, with enhanced hybridization leading to high carrier mobilities and coherent band-like electronic transport.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Materials Research and Engineering, Agency for Science Technology and Research, 2 Fusionopolis Way, 08-03 Innovis, Singapore 138634, Singapore.
Thermoelectric properties of conducting polymers typically suffer from molecular chain disordering, as charge transport is predominantly controlled by morphology. This is especially more problematic when counterions are introduced to tune the carrier concentration for optimal thermoelectric performance, which disturbs the morphology further. In this work, we introduce a new avenue for enhancing thermoelectric properties without needing to regulate the morphology, namely, by controlling the coulombic interaction between polarons and counterions.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Nanjing University, National Laboratory of Solid State Microstructures & Department of Materials Science and Engineering, Nanjing 210093, China.
Precisely engineered gigahertz surface acoustic wave (SAW) trapping enables diverse and controllable interconnections with various quantum systems, which are crucial to unlocking the full potential of phonons. The topological rainbow based on synthetic dimension presents a promising avenue for facile and precise localization of SAWs. In this study, we successfully developed a monolithic gigahertz SAW topological rainbow by utilizing a nanoscale translational deformation as a synthetic dimension.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!