AI Article Synopsis
- - A new reaction method has been developed to create N-acyl imidazoles and triazoles using natural light and DMSO/O-catalysis, occurring at room temperature without any metals.
- - This method is both environmentally friendly and efficient, featuring benefits like minimal waste, high yields, and the ability to work with a variety of chemical groups.
- - The resulting compounds show good photocurrent and electrochemical properties, making them promising candidates for use in biosensor materials.
Article Abstract
An unprecedented natural light promoted DMSO/O-catalyzed N-acylation reaction of imidazoles/triazoles with cyclopropenones at room temperature under metal-free conditions has been developed. The remarkable advantages of this strategy include atomic economy and environmentally benign conditions (such as natural light promotion, DMSO/O-catalysis, room temperature, and DMC as solvent), stereospecific (E)-olefins synthesis (N-acyl imidazoles and triazoles), wide functional group tolerance and high reaction yields. Furthermore, the typical products (1c and 1e) display good photocurrent and electrochemical property and are potentially applicable in biosensor materials fields.
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| http://dx.doi.org/10.1007/s11030-024-11039-9 | DOI Listing |
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