The L-shell x-ray emission of tellurium induced by H ions impact is investigated in an energy range of 150-300 keV. The blue shifts of various L-subshell x rays and the enhancement of the relative intensity ratios of Lι, Lβ to Lα x ray are observed and interpreted by the multiple ionization of outer-shell electrons. The new experimental x-ray production cross sections, which almost correspond to those of protons with half of the original energy, are extracted and compared with various theoretical estimations. The correction effects of the united atom approximation and the multiple ionization atomic parameters are compared, and the influence of atomic parameters from different databases on the simulations is discussed. Overall, the ECUSAR-MI calculations using theoretical atomic parameters present the best agreement with the experiment results.
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http://dx.doi.org/10.1038/s41598-024-80191-x | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
December 2024
School of Agriculture and Bioengineering, Heze University, Heze 274500, China. Electronic address:
Herin, the successful synthesis of a bis Schiff base (L) has been achieved using 2-hydroxy-1-naphthaldehyde and 1,3-diaminoguanidine as raw materials, which was further characterized by infrared spectroscopy, mass spectrometry, and nuclear magnetic resonance hydrogen spectrum. Moreover, spectroscopic experiments demonstrated that the probe L showed good selectivity and visual detectability for Al. Its detection limit (DL) is 2.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 214122 Jiangsu, China.
Nanometric solid solution alloys are utilized in a broad range of fields, including catalysis, energy storage, medical application, and sensor technology. Unfortunately, the synthesis of these alloys becomes increasingly challenging as the disparity between the metal elements grows, due to differences in atomic sizes, melting points, and chemical affinities. This study utilized a data-driven approach incorporating sample balancing enhancement techniques and multilayer perceptron (MLP) algorithms to improve the model's ability to handle imbalanced data, significantly boosting the efficiency of experimental parameter optimization.
View Article and Find Full Text PDFSci Rep
December 2024
School of Chemical Engineering, Iran University of Science and Technology (IUST), Tehran, Iran.
Benzene separation from hydrocarbon mixtures is a challenge in the refining and petrochemical industries. The application of liquid-liquid extraction process using ionic liquids (I.Ls) is an option for this separation.
View Article and Find Full Text PDFSci Rep
December 2024
Department of Mathematics, Payame Noor University, Tehran, Iran.
In the realm of petroleum extraction, well productivity declines as reservoirs deplete, eventually reaching a point where continued extraction becomes economically unfeasible. To counteract this, artificial lift techniques are employed, with gas injection being a prevalent method. Ideally, unrestricted gas injection could maximize oil output.
View Article and Find Full Text PDFJ Mol Graph Model
December 2024
Department of Chemistry, Faculty of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh,11623, Saudi Arabia. Electronic address:
The work being presented now combines severe gradient boosting with Shapley values, a thriving merger within the field of explainable artificial intelligence. We also use a genetic algorithm to analyse the HDAC1 inhibitory activity of a broad pool of 1274 molecules experimentally reported for HDAC1 inhibition. We conduct this analysis to ascertain the HDAC1 inhibitory activity of these molecules.
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