Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3098
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Severity: Warning
Message: Attempt to read property "Count" on bool
Filename: helpers/my_audit_helper.php
Line Number: 3100
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3100
Function: _error_handler
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
The synthesis of primary amines from renewable biomass and its derivatives through reductive amination has garnered significant attention. How to construct efficient non-noble-metal catalysts that enable low-temperature catalysis still remains challenging. Herein, we report a Cu-doped Co@CoO heterostructure catalyst that features structural Co-CoCuO bifunctional sites, which enable room temperature reductive amination of various aldehydes with 1.57-45 times higher efficiency than Co@CoO , outperforming many reported non-noble and even noble metal catalysts. Experiments and DFT calculations indicate that Cu doping leads to a phase transition of Co from hcp to fcc, while electrons are transferred from Cu to Co, forming a dual active site with electron-rich Co closely interacting with CoCuO . These electron-rich Co sites demonstrate excellent activity in the activation and dissociation of hydrogen, while the CuO component facilitates hydrogen spillover at the CoCuO interface, thus resulting in a highly efficient cooperative effect for the furfural (FAL) reductive amination. This work provides general guidance for the rational design of high-performance reductive amination catalysts for biomass upgrading.
Download full-text PDF |
Source |
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11577266 | PMC |
http://dx.doi.org/10.1039/d4sc05885b | DOI Listing |
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