Simulations of single photon avalanche diodes (SPADs) based on the Ge-on-Si material platform are presented, highlighting the potential performance enhancement achievable with nano-hole array photonic crystal structures. Such structures can be used to enhance photon absorption and therefore increase single photon detection efficiencies (SPDE). However, there is yet to be a study of these structures in application to Ge-on-Si SPADs to determine if the optical enhancements can be realized as SPDE or to evaluate the change in dark count rate due to the nano-holes that form the photonic crystal. This work establishes an optimization and analysis platform for investigating photonic crystal structures on SPAD devices. Both a direct Ge etch method, and an etched amorphous Si design are compared to a reference device with an optimized anti-reflection coating. Finite difference time domain simulations were used to optimize the photonic crystal parameters for these structures, finding a potential absorption of up to 37.09 % at wavelengths of 1550 nm for a 1 µm absorption layer, compared to 11.33 % for the reference device. Subsequently, TCAD simulations and custom code were used to calculate the effective enhancement to SPAD performance metrics, as a function of material and passivation quality, showing up to 2.41x higher SPDE and 2.57x better noise-equivalent power is achievable provided etched surfaces are sufficiently well passivated.
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Mater Horiz
January 2025
Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Beijing Advanced Innovation Center for Imaging Theory and Technology, Capital Normal University, Beijing 100048, P. R. China.
Linearly-polarized organic electroluminescent devices have gained significant attention due to their potential applications across various fields. However, traditional thin-film organic light-emitting diodes (OLEDs) face significant challenges, primarily due to the necessity of incorporating complex optical elements. In this study, we present linearly-polarized OLEDs (LP-OLEDs) based on organic single crystals that we have designed and prepared.
View Article and Find Full Text PDFACS Nano
January 2025
School of Information Science and Technology and Department of Optical Science and Engineering and Key Laboratory of Micro and Nano Photonic Structures (MOE), Fudan University, Shanghai 200433, China.
The formation of large polarons resulting from the Fröhlich coupling of photogenerated carriers with the polarized crystal lattice is considered crucial in shaping the outstanding optoelectronic properties in hybrid organic-inorganic perovskite crystals. Until now, the initial polaron dynamics after photoexcitation have remained elusive in the hybrid perovskite system. Here, based on the terahertz time-domain spectroscopy and optical-pump terahertz probe, we access the nature of interplay between photoexcited unbound charge carriers and optical phonons in MAPbBr within the initial 5 ps after excitation and have demonstrated the simultaneous existence of both electron- and hole-polarons, together with the photogenerated carrier dynamic process.
View Article and Find Full Text PDFACS Mater Au
January 2025
Liquid Crystal Research Laboratory, Department of Physics, University of Lucknow, Lucknow, Uttar Pradesh 226007, India.
Polymer-dispersed liquid crystals (PDLCs) stand at the intersection of polymer science and liquid crystal technology, offering a unique blend of optical versatility and mechanical durability. These composite materials are composed of droplets of liquid crystals interspersed in a matrix of polymeric materials, harnessing the optical properties of liquid crystals while benefiting from the structural integrity of polymers. The responsiveness of LCs combined with the mechanical rigidity of polymers make polymer/LC composites-where the polymer network or matrix is used to stabilize and modify the LC phase-extremely important for scientists developing novel adaptive optical devices.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
College of Materials and Textile Engineering, Jiaxing University, Jiaxing 314001, China.
Programmable organization of uniform organic/inorganic functional building blocks into large-scale ordered superlattices has attracted considerable attention since the bottom-up self-organization strategy opens up a robust and universal route for designing novel and multifunctional materials with advanced applications in memory storage devices, catalysis, photonic crystals, and biotherapy. Despite making great efforts in the construction of superlattice materials, there still remains a challenge in the preparation of organic/inorganic hybrid superlattices with tunable dimensions and exotic configurations. Here, we report the spontaneous self-organization of polystyrene-tethered gold nanoparticles (AuNPs@PS) into freestanding organic/inorganic hybrid superlattices templated at the diethylene glycol-air interface.
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January 2025
Ministry of Industry and Information Technology Key Lab of Micro-Nano Optoelectronic Information System, Guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic Systems, Harbin Institute of Technology (Shenzhen), Shenzhen, Guangdong 518055, China.
The power conversion efficiencies (PCEs) of polycrystalline perovskite solar cells (PC-PSCs) have now reached a plateau after a decade of rapid development, leaving a distinct gap from their Shockley-Queisser limit. To continuously mitigate the PCE deficit, nonradiative carrier losses resulting from defects should be further optimized. Single-crystal perovskites are considered an ideal platform to study the efficiency limit of perovskite solar cells due to their intrinsically low defect density, as demonstrated in bulk single crystals.
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