A hundred-watt-level peak-power linearly polarized Ho,Pr:GdScO laser with narrow pulses was first realized at ∼3 µm through a combination of theoretical simulation and experiment. This is the narrowest pulse width, and the highest peak power has been achieved in a passively pulsed Ho,Pr co-doped laser to date. We realized a linearly polarized narrow-pulsed laser at ∼3 µm, with a maximum peak power of 185 W and shortest pulse width of 42 ns. A further theoretical model was built by simulating the dynamic process of the mid-infrared (MIR) pulsed Ho,Pr:GdScO laser using coupled rate equations. The numerical simulation results were fundamentally in agreement with the experimental results, which verified the potential of Ho,Pr:GdScO crystals to produce sub-50-ns hundred-watt peak power MIR lasers. The results presented an effective way to achieve high-peak-power, narrow-pulse, and linearly-polarized lasers, which have significant research potential and promising applications in the MIR band.
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http://dx.doi.org/10.1364/OE.542304 | DOI Listing |
Mater Horiz
January 2025
Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, China.
Dynamic responsive structural colored materials have drawn increased consideration in a wide range of applications, such as colorimetric sensors and high-safety tags. However, the sophisticated interactions among the individual responsive parts restrict the advanced design of multimodal responsive photonic materials. Inspired by stimuli-responsive color change in chameleon skin, a simple and effective photo-crosslinking strategy is proposed to construct hydroxypropyl cellulose (HPC) based hydrogels with multiple responsive structured colors.
View Article and Find Full Text PDFAchiral metasurfaces with near-field optical chirality have attracted great attention in molecular sensing and chiral emission control. Here, the circular dichroism (CD) response of an achiral metasurface induced by spatially selective coupling with polymethyl methacrylate (PMMA) molecules is demonstrated. A designed achiral metasurface with a V-shaped resonator exhibits large optical chirality with a strongly dissymmetric distribution under circular polarization.
View Article and Find Full Text PDFMetasurfaces offer a powerful tool to realize label-free and highly sensitive Raman spectroscopy. Embedding metasurfaces into microfluidic channels is promising to establish a new characterizing platform for microfluids. In this Letter, we present a highly stable method for improving the Raman scattering intensity of biological microfluids by using a microfluidic chip embedded with a plasmonic metasurface.
View Article and Find Full Text PDFOn-chip spin-exchange relaxation-free (SERF) atomic magnetometers (AMs) require linearly polarized light as detection light whose wavelength is 795 nm. In this study, we propose and demonstrate an inverse-designed linearly polarized light emitter suitable for 795 nm wavelength light. Due to the fact that the electric field of the TE fundamental mode is almost a beam of linearly polarized light, we verified whether the emission light obtained when only coupling efficiency is taken as the objective function is linearly polarized.
View Article and Find Full Text PDFChemphyschem
January 2025
University of Namur, Department of Chemistry, Rue de Bruxelles, 61, 5000, Namur, BELGIUM.
The [4+2] Diels-Alder cycloaddition reaction between 2,5-DMF (1) and ethylene derivatives (2a-h) activated by electron-withdrawing groups has been studied at the density functional theory levels using a panoply of tools to unravel the reaction mechanisms. From the analysis of the reactivity indices, 2a-h behave as electrophiles while 1 as nucleophile, and the activation of the double bond of ethylene increases its electrophilicity, which is accompanied by an enhancement of the polarity of the reaction. The activation Gibbs free energy decreases linearly as a function of this increase of polarity, as estimated by the electrophilicity difference between the reactants.
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