Identifying the handedness of chiral materials in small quantities remains a significant challenge in biochemistry. Nanophotonic structures offer a promising solution by enhancing weak chiroptical responses through increased optical chirality. Utilizing a silicon-based approach for chiral sensing on a photonic integrated platform is highly desirable. In this study, we explore the interaction between a dielectric waveguide and silicon nanoparticles for detecting the handedness of chiral analytes. A chiral core induces polarization rotation of wavefields traveling along a dielectric waveguide with a square cross-section. This polarization rotation affects waveguide coupling differently depending on the left- or right-handed arrangement of nanoparticles around the waveguide, enabling enantiomer detection through discernible transmission differences. From a basic design to more practical structures, we investigate configurations that maintain the same working principles. Theoretical results based on the transfer matrix method corroborate the numerical simulations.
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http://dx.doi.org/10.1364/OE.538940 | DOI Listing |
ACS Nano
January 2025
College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources, Wuhan University, Wuhan 430072, China.
Chiral plasmonic nanomaterials with fascinating physical and chemical properties show emerging chirality-dependent applications in photonics, catalysis, and sensing. The capability to precisely manipulate the plasmonic chirality in a broad spectral range plays a crucial role in enabling the applications of chiral nanomaterials in diverse and complex scenarios; however, it remains a challenge yet to be addressed. Here we demonstrate a strategy to significantly enhance the tunability of circular dichroism (CD) spectra of chiral nanomaterials by constructing core-shell hybrid metal-semiconductor structures with tailored shells.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, PR China. Electronic address:
Multidirectional strain sensors are of technological importance for wearable devices and soft robots. Here, we report that flexible materials capable of multidirectional anisotropic strain sensing can be constructed leveraging diffusion-induced infiltration of monomers and in situ polymerization of metal ion-containing double network hydrogels in and on the surface of micro-corrugated chiral nematic cellulose nanocrystal/glucose films. Integrating the micro-corrugated cellulose nanocrystal/glucose chiral nematic films with ionic conductive hydrogels of PAA-co-AAm/sodium alginate/Al endows the materials with multidirectional mechanoelectrical resistivity and mechanochromism anisotropy.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Okayama Daigaku Daigakuin Shizen Kagaku Kenkyuka, Division of Applied Chemistry, JAPAN.
Intramolecular aromatic oxidative coupling of 3,6-bis(m-terphenyl-2'-yl)carbazole provided a bis(m-terphenyl)-fused carbazole, while that of 3,6-bis(m-terphenyl-2'-yl)-1,8-diphenylcarbazole afforded a bis(quaterphenyl)-fused carbazole. Borylation of the latter furnished a B,N-embedded helical nanographene binding a fluoride anion via a structural change from the three-coordinate boron to the four-coordinate boron. The anionic charge derived from the fluoride anion is stabilized over the expanded p-framework, which leads to the high binding constant (Ka) of 1 × 105 M-1.
View Article and Find Full Text PDFOrg Lett
January 2025
Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904, United States.
Highly fluorinated naphthyl aldehyde and binaphthyl aldehyde ()- were designed and synthesized for fluorous-phase-based sensing. Greatly enhanced sensitivity and chemoselectivity in going from to ()- in the fluorescent detection of cysteine has been discovered. This is attributed to the increased structural rigidity of the axially chiral binaphthyl unit in ()- upon reaction with cysteine to form the corresponding thiazolidine product.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Department of Chemistry, Khalifa University, SAN Campus, Abu Dhabi, United Arab Emirates.
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