Regulation of electron density in Pt nanoparticles via bimetallic metal-organic frameworks for enhancing photothermal catalysis of toluene decomposition.

Volatile Organic Compounds (VOCs) are omnipresent in the sphere of human industrial, harboring latent adverse consequences for health and the ecological system. The photothermal catalytic oxidation of VOCs is an advanced integrated technology that harnesses the combined effects of light and heat energy to enhance the efficiency of VOCs degradation. Herein, a bimetallic Metal-Organic Framework (MOF) was synthesized with the incorporation of Ce into the UiO-66-NH(Zr) (i.e., UNH(Zr)), UiO-66-NH(ZrCe) (i.e., UNH(ZC)), which was achieved with Ce atom substituting for a portion of Zr atom within the Zr-oxo clusters. Pt nanoparticles (NPs) are integrated with MOFs to form composites using the dual-solvent method. Ce-oxo fulfills a bifunctional role: it not only facilitates the enhancement of the ligand-to-metal charge transfer (LMCT), but also establishes interaction with Pt NPs. Ce-oxo mediates an enhancement of electron density on Pt NPs. This phenomenon enhances the adsorption and activation of oxygen, significantly boosting the photocatalytic performance for toluene degradation, as demonstrated by a reduction of 30 ℃ for complete mineralization of toluene as compared to that of Pt@UiO-66-NH(Zr) (i.e., PUNH(Zr)). This study potentially offers new insights into the relationship between electron transfer effects in bimetallic MOF-based catalysts and their efficient catalytic performance for VOCs degradation.