This paper presents the synthesis of mixed metal oxide (BaTiO: ZnO) (B: Z) sensors with various molar ratios using a low-temperature hydrothermal method for dual sensing applications (gas and acceleration). The sensor developed with an equal molar ratio of 1B:1Z, showcases superior performance compared to unmixed and alternative mixed metal oxide sensors. This equilibrium in ratios optimally enhances synergistic effects between elements B and Z, resulting in improved sensing properties. Furthermore, it contributes to structural stability, enhancing performance in gas and acceleration sensing. A decreased band gap of 2.82 eV and a rapid turn-on voltage of 0.18 V were achieved. The acceleration performance of 1B:1Z sensor exhibits a maximum voltage of 2.62 V at a 10 Hz resonant frequency and an output voltage of 2.52 V at 1 g acceleration, achieving an improved sensitivity of 3.889 V g. In addition, the proposed gas shows a notable sensor response of ∼63.45% (CO) and 58.29% (CH) at 10 ppm with a quick response time of 1.19 s (CO) and 8.69 s (CH) and recovery time of 2.09 s (CO) and 8.69 s (CH). Challenges in selectivity are addressed using machine learning, employing various classification algorithms. Linear discriminant analysis achieves superior accuracy in differentiating between CO and CHreaching 96.6% for CO and 74.6% for CHat 10 ppm. Understanding these concentration-dependent trends can guide the optimal use of the sensors in different current applications.
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Int J Phytoremediation
January 2025
Institute of Soil & Environmental Sciences, University of Agriculture, Pakistan.
Due to a lack of high-quality water, farmers have been compelled to use sewage water for irrigation, contaminating agricultural soils with multiple heavy metals. For the remediation of contaminated soil, plant growth-promoting rhizobacteria (PGPR), pressmud (PM), and iron (III) oxide were used to improve the growth and phytostabilization potential of chickpea grown in contaminated soil. Contaminated soil was collected from a nearby field, receiving sewage and factory water over the last 60 years.
View Article and Find Full Text PDFNano Lett
January 2025
Departments of Chemistry, and Physics and Astronomy, University of Southern California, Los Angeles, California 90089, United States.
A-site cations in ABX metal halide perovskites do not contribute to the frontier electronic states. They influence optoelectronic properties indirectly through interaction with the BX sublattice. By systematically investigating correlated motions of Cs cations and the PbX lattice (X = Cl, Br, I), we demonstrate that the interaction between the two subsystems depends on electronegativity and size of the X-site anion.
View Article and Find Full Text PDFKardiol Pol
January 2025
Department of Coronary and Structural Heart Diseases, National Institute of Cardiology, Warszawa, Poland.
Background: Preliminary research indicates that higher iron levels are associated with worse outcomes in patients with coronary artery disease.
Aims: The study aimed to investigate the relationship between iron levels and the type and composition of coronary plaques.
Methods: In patients with ≥1 coronary stenosis ≥50% on computed tomography angiography, iron levels, presence of high-risk plaque features, such as low-attenuation plaque (LAP), napkin-ring sign, positive remodeling, and spotty calcium, as well as type and plaque composition (calcified/fibrous/fibro-fatty/necrotic core) were evaluated.
J Colloid Interface Sci
December 2024
The Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, PR China; School of Materials Science and Engineering, North Minzu University, Yinchuan 750021, PR China. Electronic address:
Metal-phenolic networks (MPNs) are supramolecular materials that have received interest in various fields, including biomedicine, separations, environmental remediation, and catalysis. Despite recent advances, the construction of thick and robust MPN coatings that withstand harsh conditions (e.g.
View Article and Find Full Text PDFACS Omega
December 2024
Grupo de Química de Coordenação e Espectroscopia de Lantanídeos (GQCEL), Instituto de Química, Universidade do Estado do Rio de Janeiro, Rio de Janeiro, RJ 20550-013, Brazil.
Metal-organic frameworks (MOFs) are coordination polymers that can generally be described by secondary building units (SBUs). These include lanthanide MOFs, specifically mixed lanthanide MOFs (m-LnMOFs), encompassing coordination polymers formed by two or more different Ln ions. These compounds have been the subject of study by inorganic chemists worldwide, mainly due to the possibility of obtaining long-awaited tunable luminescence, i.
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