We synthesized phosphanylphosphaalkenes (biph)CP-P(Bu) (2), PhCP-P(NEt) (3), and (biph)CP-P(NEt) (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P-P bond activation and the formation of a bridging phospaalkene complex under mild conditions.
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Phosphanylphosphaalkenes as precursors for metallaphosphaalkene complexes.
Dalton Trans
December 2024
Gdansk University of Technology, Faculty of Chemistry, Department of Inorganic Chemistry, Gabriela Narutowicza Str. 11/12, 80-233 Gdansk, Poland.
We synthesized phosphanylphosphaalkenes (biph)CP-P(Bu) (2), PhCP-P(NEt) (3), and (biph)CP-P(NEt) (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P-P bond activation and the formation of a bridging phospaalkene complex under mild conditions.
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