When analysing the effect of negative temperature on overwintering pit constructions of unsaturated soil, using the mechanical parameter of saturated soil at room temperature leads to an inaccuracy in the research findings. The strength parameters are obtained through indoor experiments. The foundation pit model is created using FLAC3D numerical simulation software based on the indoor experimental data. The influence of different parameters on the stress and deformation of the overwintering deep foundation pit supporting structure is analysed. The numerical simulation results obtained are compared with the actual monitoring data. According to research, the matric suction of the silty clay in its natural state in the Changchun area is 70 kPa. As the temperature decreases, the total cohesion of the unsaturated soil increases, and the internal friction angle tends to decrease. The numerical simulation results are consistent with the actual monitoring data changes. With the excavation, the horizontal displacement of the supporting structure increases first and then decreases, reaching the maximum displacement at two-thirds of the foundation pit. Compared with room temperature, the deformation of the supporting structure is larger under a negative temperature condition. The deformation of the supporting structure simulated by the actual temperature mechanical parameters is larger than that under the condition of normal temperature mechanical parameters. The frost-heaving force increases with the overall excavation, and a surge occurs at the bottom of the pit. The frost-heaving force changes most significantly under the condition of freezing at -20°C for 30 days.
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http://dx.doi.org/10.1098/rsos.240992 | DOI Listing |
ACS Mater Lett
January 2025
Department of Chemistry, Durham University, Durham, DH1 3LE, U.K.
The study of structure-activity relationships is a top priority in the development of nontraditional luminescent materials. In this work, nonconjugated polyurethanes (PUs) with full-color emission (red, green, and blue) are easily obtained by control of the diol monomer structure and the polymerization conditions. Selected diol monomers introduced single, double, or triple bond repeating units into the main chain of the PUs, in order to understand how unsaturated bonds and H-bonds affect their luminescence from a molecular orbital viewpoint.
View Article and Find Full Text PDFSoft Matter
January 2025
Faculty of Mathematics and Physics, University of Ljubljana, Jadranska 19, 1000 Ljubljana, Slovenia.
We demonstrate the generation of diverse material flow regimes in nematic liquid cells as driven by time-variable active surface anchoring, including no-net flow, oscillatory flow, steady flow, and pulsating flow. Specifically, we numerically simulate a passive nematic fluid inside a cell bounded with two flat solid boundaries at which the time-dependent anchoring is applied with the dynamically variable surface anchoring easy axis. We show that different flow regimes emerge as the result of different anchoring driving directions ( co-rotating or counter-rotating) and relative phase of anchoring driving.
View Article and Find Full Text PDFACS Nano
January 2025
Instituto de Física de São Carlos, Universidade de São Paulo, São Carlos 13566-590, Brazil.
Monolayers of transition-metal dichalcogenides, such as MoS, have attracted significant attention for their exceptional electronic and optical properties, positioning them as ideal candidates for advanced optoelectronic applications. Despite their strong excitonic effects, the atomic-scale thickness of these materials limits their light absorption efficiency, necessitating innovative strategies to enhance light-matter interactions. Plasmonic nanostructures offer a promising solution to overcome those challenges by amplifying the electromagnetic field and also introducing other mechanisms, such as hot electron injection.
View Article and Find Full Text PDFBMC Med Res Methodol
January 2025
School of Mathematical Sciences, Xiamen University, Xiamen, 361005, People's Republic of China.
Objective: To assess whether the outcome generation true model could be identified from other candidate models for clinical practice with current conventional model performance measures considering various simulation scenarios and a CVD risk prediction as exemplar.
Study Design And Setting: Thousands of scenarios of true models were used to simulate clinical data, various candidate models and true models were trained on training datasets and then compared on testing datasets with 25 conventional use model performance measures. This consists of univariate simulation (179.
Sci Rep
January 2025
Key Laboratory of Urban and Architectural Heritage Conservation, Ministry of Education, School of Architecture, Southeast University, 2# Sipailou, Nanjing, 210096, China.
This paper presents a microperforated panel (MPP) sound absorber with parallel coiled-up-cavities of different-depths (PCD) and the corresponding optimization on their cavities. In this study, an analytical model is initially proposed for estimating the cavity depths of the PCD-MPP absorber upon normal incidence absorption coefficient evaluation at given resonance frequencies. Cavity effective depths and normal incidence absorption coefficient are evaluated after coiling up cavities for a compact structure.
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