Extensive efforts are being made globally to install units to remediate contaminants in groundwaters used for drinking, but are these units being installed in the optimum locations? Here, we explore this question for Bihar, an eastern Indian state with a high reliance on groundwater for drinking water. Bihar is impacted by groundwater quality issues, notably in relation to the geogenic contaminants arsenic (As), iron (Fe) and fluoride (F). We map the distribution of groundwater quality remediation units for As, Fe and F, and which were implemented from 2016 by the Government of Bihar under the aegis of the Public Health Engineering Department (PHED). The majority of the reported remediation units for As are within a distance of 10 km from the main branch of the River Ganges (Ganga), whereas the remediation units for Fe are exclusively present in the eastern and north-eastern districts of Bihar. All of the remediation units for F are located in districts south of the River Ganges. The distributions of the installed remediation units are compared with the distribution and concentration of the target contaminants based on a representative Bihar-wide groundwater sampling campaign reported previously by our group. Inconsistencies are identified in many cases between the distribution of implemented remediation units and areas where elevated levels of the contaminant have been found. Some possible reasons for the apparent mismatches are discussed and include: prioritizing installation on the basis of now out-of-date contaminant distribution maps based on strongly non-representative sampling strategies, and administrative and operational convenience. Our study highlights that there are likely extensive areas in Bihar with groundwater quality issues where necessary interventions are required, but not yet received, whilst there seems to be widespread installation of remediation units where the need is less indicated. Several recommendations are made, including the need for representative, broad-scale (e.g. state-wide) testing to underpin robust decision making for optimal site selection for remediation unit installation for improved drinking water.
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http://dx.doi.org/10.1016/j.jenvman.2024.123157 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Eberhard Karls Universität Tübingen: Eberhard Karls Universitat Tubingen, Institut für Organische Chemie, Auf der Morgenstelle 18, 72076, Tübingen, GERMANY.
The direct incorporation of borondipyrromethene (BODIPY) subunits into the structural backbone of covalent organic frameworks (COFs) gives facile access to porous photosensitizers but is still a challenging task. Here, we introduce β‑ketoenamine-linked BDP‑TFP‑COF, which crystallizes in AA‑stacking mode with hcb topology. A comprehensive characterization reveals high crystallinity and enhanced stability in a variety of solvents, excellent mesoporosity (SABET = 1042 m2 g-1), broad light absorption in the visible region, and red emission upon the exfoliation of few-layer COF nanosheets.
View Article and Find Full Text PDFMolecules
December 2024
Dipartimento di Chimica e Biologia, and INSTM Research Unit, Università di Salerno, Via Giovanni Paolo II 132, I-84084 Fisciano, SA, Italy.
Plastic pollution is a global problem affecting the environment and, consequently, people's well-being. Careful and timely end-of-life plastic recycling is certainly a way, albeit a partial one, to remedy the problem. The immediate identification and selection of the different types of plastic materials in the recycling process certainly facilitate its recovery and reuse, allowing the damage caused by plastic emission into the environment to be limited.
View Article and Find Full Text PDFEcotoxicol Environ Saf
January 2025
College of Resources, Sichuan Agricultural University, Chengdu 611130, China.
Immobilization remediation is a widely employed technology that effectively reduces the migration rate and bioavailability of cadmium (Cd). Sepiolite, a commonly used remediation agent, has proven effective in decreasing soil Cd availability and reducing Cd accumulation in agricultural products. However, further investigation is needed to understand the impact of sepiolite on soil environmental quality and microbial communities.
View Article and Find Full Text PDFJ Urban Health
January 2025
Department of Epidemiology, Mailman School of Public Health, Columbia University, New York, NY, USA.
Community violence is a major cause of injury and death in the USA. Empirical studies have identified that some place-based interventions of urban private places, such as remediations of vacant lots and buildings, are associated with reductions in community violence in surrounding areas. The aim of this study was to examine whether routine maintenance and repair of urban public places (e.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry and Bioscience, Kumoh National Institute of Technology, Gumi 39177, Republic of Korea.
Porphyrin-based two-dimensional porous materials (SnP-H2TCPP, SnP-ZnTCPP) composed of robust Sn(IV)-porphyrin linkages have been synthesized by reacting -dihydroxo[5,10,15,20-tetraphenylporphyrinato]tin(IV) (SnP) with [5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin] (HTCPP) and [5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato]zinc(II) (ZnTCPP), respectively. The strength of the interaction between the carboxylic acid group of the monomeric porphyrins (HTCPP and ZnTCPP) and the axial hydroxyl moiety of SnP enables the construction of highly stable framework materials, which were characterized by FT-IR, UV-vis, and emmission spectroscopy, powder XRD, elemental analysis, and thermogravimetric analysis (TGA). SnP-H2TCPP and SnP-ZnTCPP absorb visible light strongly over a wide range, demonstrating weak perturbation in the electronic ground state structures of the π-conjugated aromatic moieties compared to the starting monomeric units.
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