Incorporating Mixed-Ligand Zeolitic Imidazolate Framework into Polydimethyldiethoxysilane (PDMDES) Membrane for Enhancing Alcohol Pervaporation Recovery.

In the present study, a zeolitic imidazolate framework with mixed ligands, ZIF-8-90, was synthesized and embedded into an ultrathin polydimethyldiethoxysilane (PDMDES) matrix to prepare a ZIF-8-90/PDMDES mixed matrix membrane (MMM) for the enhanced recovery of alcohols from dilute aqueous solutions via pervaporation, using a facile solution coating method. The synthesized ZIF-8-90 particles demonstrated superior hydrophobicity and thermal stability compared to those of both ZIF-8 and ZIF-90 particles. Furthermore, the hydrophobicity, thermal stability, and sorption ability for alcohols of the ZIF-8-90/PDMDES MMM were significantly improved, attributed to the incorporation of mixed-ligand ZIF-8-90. Notably, the MMMs displayed two distinct cross-sectional morphologies: (1) ZIF-8-90 particles enveloped by PDMDES polymer forming filler bulges and (2) an accumulation of ZIF-8-90 particles resembling a brick-wall-like structure. The MMM incorporating 2.5 wt % ZIF-8-90 exhibited the optimal performance among the fabricated MMMs with various ZIF-8-90 loadings, spanning from 0 to 3.2 wt %. The effects of feed concentrations and operation temperatures were systematically investigated. The best pervaporation performance was achieved using the 2.5 wt % ZIF-8-90-filled MMM, effectively separating a 5.0 wt % ethanol/water mixture at 60 °C, yielding a distinguished total flux of 7.70 kg·m·h, an improved separation factor of 9.96, and an extraordinarily high PSI of 68.99 kg·m·h. Comparative analyses highlighted the superior pervaporation performance of the ZIF-8-90/PDMDES MMM over ZIF-8/PDMDES MMM, ZIF-90/PDMDES MMM, and other MMMs, underscoring its potential for practical applications in alcohol recovery.