Continuous solid-phase extraction spectroscopy and its quantification method for trace analysis.

Spectrochim Acta A Mol Biomol Spectrosc

College of Chemical and Molecular Engineering, East China University of Science and Technology,130 Meilong Rd, Shanghai 200237, China.

Published: February 2025

AI Article Synopsis

  • Developed a novel online detection device using Continuous Solid-Phase Extraction Spectroscopy (CSPES) for fast analysis of water pollutants.
  • Created a reliable quantitative analysis model that correlates spectrum data with pollutant concentrations, validated through testing with multiple chemical samples.
  • Showed strong predictive accuracy with low relative errors and high recovery rates, making it a valuable tool for environmental monitoring and analysis across different sectors.

Article Abstract

This study designed and developed an innovative online detection device based on Continuous Solid-Phase Extraction Spectroscopy (CSPES) for rapid quantitative analysis of environmental water pollutants. The device is highly automated, eliminating environmental interference. Leveraging CSPES technology and adsorption kinetics theory, an online quantitative analysis model between the spectrum and component concentrations was established, along with a concentration calculation method based on the least squares method. The quantitative analysis method was validated using single-component and binary-component sample systems containing Fluoranthene, Benzo[k]Fluoranthene, and Rhodamine 6G. The model exhibited excellent predictive performance, with overall prediction concentration relative errors (RE) ranging from 0.45 % to 8.75 % and relative standard deviations (RSD) of less than 3 %. In real sample applications, recovery rates ranged from 86.8 % to 124.4 %, with RSDs between 0.33 % and 2.22 %. This method provides a robust tool for water quality monitoring and environmental analysis, holding significant potential for application across various fields.

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http://dx.doi.org/10.1016/j.saa.2024.125396DOI Listing

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