In any physical system where a surface is hit by electrons, the sticking probability s of the electrons is a central parameter governing, for example, the charging of the surface. For dielectrics, it could previously only be measured for high energies (>100 eV), while it is well-known for metals even at energies of only a few eV. Recent theoretical investigations concerning dielectrics such as silica predict values for s significantly below 1. With precision charge measurements on microparticles in the sheath of a low-pressure plasma, a difference in charge between silica and gold-coated particles is found, challenging the long-standing assumption in dusty plasma physics that dielectric and metallic particles charge in the same way for the first time. Based on the measured charging difference, the low-energy sticking coefficient of silica is obtained, validating the theoretical predictions and offering a new diagnostic for the otherwise quasi-inaccessible low-energy electron sticking of dielectric materials.
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http://dx.doi.org/10.1103/PhysRevLett.133.185301 | DOI Listing |
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January 2025
College of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China.
The development of diverse microstructures has substantially contributed to recent progress in high-performance electromagnetic wave (EMW) absorption materials, providing a versatile platform for the modulation of absorption properties. Exploring multidimensional microstructures and developing tailored and gentle strategies for their precise optimization can substantially address the current challenges posed by relatively unclear underlying mechanisms. Here, a series of 2D/1D heterogeneous NiO@PPy composites featuring hollow hierarchical microstructures are successfully synthesized using a straightforward strategy combining sacrificial templating with chemical oxidative polymerization.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Materials Science and Engineering, Northeastern University, Shenyang 110819, PR China.
The NASICON-type NaV(PO) (NVP) is recognized as a potential cathode material for Na-ion batteries (SIBs). Nevertheless, its inherent small electronic conductivity induces limited cycling stability and rate performance. Carbon coating, particularly N-doped carbon, has been identified as an effective strategy to address these challenges.
View Article and Find Full Text PDFBiofabrication
January 2025
Mechanical Engineering, National Institute of Technology Meghalaya, Shillong, Shillong, Meghalaya, 793003, INDIA.
The process of micromachining has garnered attention for its ability to create three-dimensional tiny features, particularly in ultra-hard and exotic materials. The present work investigates the effect of different parameters of the µ-ED milling, such as pulse on time (Ton), pulse off time (Toff), voltage (V), and tool rotation (TR) on the dimensional deviation (DD), material removal rate (MRR), surface roughness (Ra), and machined surface characteristics (analysed by EDS and FESEM). The sesame oil as dielectric and tungsten-copper as tool electrodes were used to maintain the accuracy and improve the machinability of bio-grade Nitinol SMA.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Electrical Engineering, Tsinghua University, Beijing, 100084, China.
As an effective method to enhance the dielectric performance of polyolefin materials, polar side group modification has been extensively applied in the insulation and energy storage materials of electrical and electronic systems. In this work, two side groups with different topological structures were adopted, namely, vinyl acetate (VAc, aliphatic chain) and -vinyl-pyrrolidone (NVP, saturated ring), to modify polypropylene (PP) chemical grafting, and the effects of structural topology of the polar side group on the microscopic and macroscopic characteristics of PP, particularly on its electrical anti-breakdown ability, were investigated. Experimental results showed that the side group structural topology directly affected the crystallization and thermal properties of PP.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
January 2025
Nanoscale Solid-Liquid Interfaces, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Schwarzschildstraße 8, 12489 Berlin, Germany.
MXenes are two-dimensional (2D) materials with versatile applications in optoelectronics, batteries, and catalysis. To unlock their full potential, it is crucial to characterize MXene interfaces and intercalated species in more detail than is currently possible with conventional optical spectroscopies. Here, we combine ultra-broadband ellipsometry and transmission spectroscopy from the mid-infrared (IR) to the deep-ultraviolet (UV) to probe quantitatively the composition, structure, transport, and optical properties of spray-coated TiCT MXene thin films with varying material properties.
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