The periodic structures are widely studied in numerous optical applications and there is a number of good tools for numerical modeling of such a structures (for example rigorous coupled-wave analysis, finite-difference time-domain, finite element method etc.). However, when it comes to the modeling of incoherent effects in many cases of practical interest, the current methods are not rigorous enough or depend on computationally demanding averaging of coherent response. In this paper, we present a novel approach to modeling of incoherent effects in structures with lateral periodicity based on scattering matrix formalism, as a way to describe optical response of a structure, and on application of incoherent wave summation in the form of infinite geometric series and generalized Mueller matrix calculus. This method can be combined with any of the existing coherent methods of modeling periodic structures and it offers significantly faster computational performance than partially coherent/incoherent methods based on averaging. It is compared with other methods for modeling of incoherent effects and also with experimental spectroscopic data. This method is then used to explain phenomena emerging from the complex interaction between diffraction grating and thick substrate.
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http://dx.doi.org/10.1364/OE.499025 | DOI Listing |
J Phys Chem Lett
January 2025
Department of Chemistry, Anhui University, Hefei 230601, P. R. China.
Despite being studied for almost two centuries, aromaticity has always been a controversial concept. We previously proposed a unified aromatic rule for π-conjugated systems by two-dimensional (2D) superatomic-molecule theory, where benzenoid rings are treated as period 2 2D superatoms (3π-N, 4π-O, 5π-F, 6π-Ne) and, further, bond to form 2D superatomic molecules. Herein, to build a 2D periodic table, we further extend the theory to period 3 (7π-P, 8π-S, 9π-Cl, 10π-Ar) and period 1 (1π-H, 2π-He) elements.
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School of Geography, Geology and the Environment, Institute for Environmental Futures, University of Leicester, Leicester, United Kingdom.
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Dept. of Psychiatry, Harvard Medical School, McLean Hospital, Belmont, Massachusetts, United States of America.
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View Article and Find Full Text PDFDiabetes Obes Metab
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