High-precision microwave spectroscopy has been used to measure the transition frequency of nS → nP (n is the principle quantum number) and further the quantum defect of nP states in a standard cesium magneto-optical trap. A microwave field with 30-μs duration coupling the nS → nP transition yields a narrow linewidth microwave spectroscopy with the linewidth approaching the Fourier limit. After carefully compensating the stray electric and magnetic field and using the diluted atomic gas, we extract improved quantum defects of nP state, δ(nP) = 3.59159091(19), δ(nP) = 0.36092(35) and δ(nP) = 3.55907153(25), δ(nP) = 0.37344(47).
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Chem Biodivers
January 2025
Department of Pharmaceutical Chemistry, MM College of Pharmacy, Maharishi Markandeshwar (Deemed to be University), Ambala, India.
Quinolone antibiotics are a crucial class of synthetic antibacterial agents, widely utilized due to their broad spectrum of antibacterial activity. Due to the development of antimicrobial resistance, the potency of quinolone drugs decreased. Many conventional methods have been developed to elevate amination rate and to improve yield.
View Article and Find Full Text PDFLangmuir
January 2025
Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, 16846-13114 Tehran, Iran.
Carbon microspheres (CMSs) are recognized as highly effective microwave absorbers due to their exceptional wave absorption properties. In this study, 5,10,15,20-tetrakis(4-aminophenyl)porphyrin, a metamaterial, was chemically bonded to CMSs─considered a conjugated carbon structure─using a 1,3-dibromopropane linker to explore the synergistic properties and microwave absorption capabilities of the synthesized composite. The synthesized structures were characterized by using X-ray diffraction, FE-SEM, Fourier transform infrared, diffuse reflectance spectroscopy, and VNA analyses.
View Article and Find Full Text PDFLuminescence
January 2025
Pharmaceutical Chemistry Department, Faculty of Pharmacy, Misr International University, Cairo, Egypt.
Affordable and eco-friendly green spectrofluorometric (FL) methods can enhance the safety and cost-effectiveness of quality assurance and control in ascorbic acid (ASA) formulations. However, most current techniques for ASA analysis have faced challenges like complexity, delayed response times, low throughput, time-consuming procedures, and requirements for expensive equipment and hazardous chemicals for analyte modification. The study is aimed at producing natural carbon quantum dots (NACQDs) from pumpkin seed peels (PSPs), a natural waste material, using a rapid microwave-assisted method.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Extreme Photonics and Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310058, China.
The continuous push for high-performance photonic switches is one of the most crucial premises for the sustainable scaling of programmable and reconfigurable photonic circuits for a wide spectrum of applications. Conventional optical switches rely on the perturbative mechanisms of mode coupling or mode interference, resulting in inherent bottlenecks in their switching performance concerning size, power consumption and bandwidth. Here we propose and realize a silicon photonic 2×2 elementary switch based on a split waveguide crossing (SWX) consisting of two halves.
View Article and Find Full Text PDFSci Rep
January 2025
Electrical Engineering Department, Kuwait University, 13060, Kuwait City, Kuwait.
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