Residue of energetic formulations, which is deposited on military training grounds following incomplete detonation, poses biotic hazards. This residue can be transported off-site, adsorb to soil clays and organic matter, transform or degrade, or taken up by plants and animals. Its harmful effects can be mitigated by localizing the energetics at the site of initial deposition using soil amendments and allowing them to bio- and photodegrade in situ. Small plots with coarse loamy soil were used to study the effect of gypsum (CaSO·2HO) on transport and redistribution under simulated rainfall of various sizes of insensitive munition explosive (IMX)-104 particles, which consist of 3-nitro-1,2,4-triazol-5-one (NTO), 2,4-dinitroanisole (DNAN), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tertranitro-1,3,5,7-tetrazocine (HMX). The addition of gypsum more than doubled infiltration and decreased sediment loss by 16% compared to the control. The post-rainfall mass balance of IMX-104 in the order from greater to smaller pools was as follows: (1) soil surface retention, (2) off-site loss to overland flow, and (3) sub-surface infiltration. Overall, the application of gypsum significantly decreased concentration and the total mass loss of dissolved DNAN, RDX, and HMX in surface runoff. In addition, gypsum significantly decreased (for NTO, DNAN, and HMX) or delayed (for NTO, DNAN, RDX, and HMX) the peak discharge of <2 mm particulate energetics. The infiltration of NTO in the gypsum treatment was fivefold greater than in the control. Moreover, DNAN and RDX were also present in infiltration, while in the gypsum-free control none were found. Gypsum shifted the total mass balance of energetics toward subsurface flow. This study indicates that gypsum may decrease off-site transport of energetic constituents in the soils that are subject to surface sealing.
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http://dx.doi.org/10.1002/jeq2.20652 | DOI Listing |
J Environ Qual
January 2025
Biosphere 2, University of Arizona, Oracle, Arizona, USA.
Residue of energetic formulations, which is deposited on military training grounds following incomplete detonation, poses biotic hazards. This residue can be transported off-site, adsorb to soil clays and organic matter, transform or degrade, or taken up by plants and animals. Its harmful effects can be mitigated by localizing the energetics at the site of initial deposition using soil amendments and allowing them to bio- and photodegrade in situ.
View Article and Find Full Text PDFEnviron Pollut
December 2024
School of Environmental Studies, Queen's University, Kingston, Ontario, Canada; Public Health Ontario, Kingston, Ontario, Canada. Electronic address:
Heliyon
August 2024
Copernicus Institute of Sustainable Development, Utrecht University, Utrecht, the Netherlands.
Water Res
October 2024
Institut Agro, UMR1069 SAS, INRAE, 65 rue de Saint-Brieuc, Rennes, CEDEX 35000, France.
The profound influence of climate change on the hydrological cycle raises concerns about its potential impacts on water quality, particularly in agricultural catchments. Here, we analysed 200 storm events monitored for nitrate and total phosphorus (TP) at sub-hourly intervals from 2016 to 2023 in the Kervidy-Naizin catchment (north-western France). Using Extreme Value theory, we identified storm events with extreme concentrations and compared their hydroclimatic characteristics to those of non-extreme events.
View Article and Find Full Text PDFJ Environ Manage
August 2024
Department of Evolutive Biology, Ecology and Environmental Sciences, University of Barcelona, 08028, Barcelona, Spain; CREAF, Spain. Electronic address:
In this work we aim to assess the impact of a WWTP effluent overland flow on properties and nutrient concentrations of a riparian soil, in order to explore the potential of this practice as a nature-based treatment. We set two study zones of 150 m on the field, one control and one that received the WWTP effluent on its surface for one month. Samples were taken before and after the effluent overland flow system, to test the impact of the effluent on soil properties through a BACI design, and after 17 months, to evaluate the recovery of the soil.
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