Marine fouling poses significant challenges to the efficiency and longevity of marine engineering equipment. To address this issue, developing effective marine antifouling coatings is critical to ensure the economic viability, environmental sustainability, and safety of offshore operations. In this study, we developed an innovative green antifouling and wear-resistant coating based on lignin, a renewable and sustainable resource. Lignin is considered environmentally friendly because it is abundant, biodegradable, and reduces reliance on petroleum-based materials. The coating was formulated with a controlled hydrophilic-to-hydrophobic ratio of 2:8, leveraging lignin's unique properties. Applying lignin increased the water contact angle by 14.5 %, improving surface hydrophobicity and contributing to the coating's antifouling efficacy. Moreover, the mechanical strength of the coating was enhanced by approximately 200 %, significantly boosting its durability in harsh marine environments. Additionally, the friction coefficient was reduced by about 85 %, further preventing organism adhesion. These results demonstrate that lignin-based coatings offer a greener alternative to traditional antifouling solutions. The results of this study not only help advance antifouling coating technology but are also consistent with the broader goal of promoting environmental responsibility in marine engineering practice.
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http://dx.doi.org/10.1016/j.ijbiomac.2024.137456 | DOI Listing |
Soft Matter
December 2024
State Key Laboratory of High-Efficiency Coal Utilization and Green Chemical Engineering, School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China.
Polyzwitterions refer to polymers containing both positive and negative charged groups in one side chain, which have shown unique physicochemical properties and significant potential in diverse applications due to their amphiphilic and net-neutral charged properties. This review aims to highlight the recent advances in the design and synthesis of polyzwitterions including direct polymerization of zwitterionic monomers and deionization of polymers. Furthermore, the formation of polyzwitterion based soft materials such as nanoparticles by self-assembly, hydrogels, coatings and polyzwitterion brushes, as well as the influence of the microstructure on their properties and applications are discussed.
View Article and Find Full Text PDFNano Lett
December 2024
Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068, P. R. China.
Poly(vinylidene fluoride) (PVDF) membranes with highly hydrophilic and antifouling properties are desirable for oily wastewater treatment. Herein, we report (1) a strategy of bulk modification of PVDF by integration of PVDF and a particle-based double-network (PDN) hydrogel, poly-2-acrylamido-2-methylpropanesulfonate/polyacrylamide (PAMPS/PAAm), via a strong PDN and PVDF interpenetrating polymer network (PDN-PVDF IPN) to obtain a PVDF/PDN solution and (2) the subsequent casting of it into a microfiltration membrane via spray-assisted non-solvent-induced phase separation (SANIPS). The IPN structure modulates the surface segregation behavior of the highly hydrophilic and robust PDN hydrogel in the process of SANIPS, endowing the resulting PVDF/PDN membrane with excellent bulk mechanical properties and much enhanced wettability and thereby high oil/water emulsion separation efficiency and antifouling performance.
View Article and Find Full Text PDFChembiochem
December 2024
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, Xiamen, 361005, China.
We report the creation of multivalent ligand surfaces for cell capture by conjugation of ligand-appended 2D peptide assemblies on an antifouling glass substrate. The sheet-like structures organize ligands into non-uniform, patchy patterns, enhancing multivalent cell targeting. A 155 % increase in captured cells was achieved compared to the presentation of the ligands on surfaces lacking the peptide sheets.
View Article and Find Full Text PDFSmall
November 2024
State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, P. R. China.
In recent years, slippery liquid infused porous surfaces (SLIPS) renowned for their exceptional liquid repellency and anti-fouling properties, have garnered considerable attention. However, the instability of both structural integrity and the oil film severely restricts their practical applications. This study is inspired by superwetting biological surfaces, such as fish scales, seashells, and Nepenthes, to design and fabricate a multiplex biomimetic and robust lubricant-infused textured surface (LITMS) using laser-coating composite processing technology.
View Article and Find Full Text PDFACS Omega
November 2024
Institute of Membrane Research, Helmholtz-Zentrum Hereon, Max-Planck-Straße 1, 21502 Geesthacht, Germany.
Thin-film composite (TFC) membranes containing metal-polyphenol network (MPN) selective layers were fabricated using a supramolecular self-assembly between tannic acid (TA) and ferric ion (Fe). The TA-Fe thin film was coated on a porous polyacrylonitrile support using aqueous solutions of TA and FeCl via a layer-by-layer deposition technique. The pH of the TA solution was used as a tool to alter the membrane characteristics.
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