Optimising microplastic polyethylene terephthalate fibre extraction from sediments: Tailoring a density-separation procedure for enhanced recovery and reliability.

Despite the presence of microplastics in sediments being widely acknowledged, the absence of standardised processing methods in extracting microplastics can compromise reliable and comparable results. Density separation is a predominant method for extracting microplastics from sediments. In this study, Sodium Polytungstate (ρ = 1.6 g cm) was selected as the density separation agent for three key factors: i) optimal density for extracting common plastic polymers, ii) low toxicity, and iii) recycling potential of the solution. It is therefore cost-effective, and the risk of solution dispersal is minimal. The solution was tested through four separation procedures, extracting PET fibres from three artificial sediment mixtures (i.e., pure sand, pure mud, and 50 % sand and 50 % mud). The results indicate that the solution employed in this work is highly effective for extracting microplastic fibres from sediments, with recovery rates up to 99 %. However, the results highlight differences in the recovery among the four procedures and in terms of the sediment characteristics. Specifically, extracting microplastics was easier in sandy sediment samples than in mud-rich ones. The complexity of extracting microplastics from mud-rich sediments results from i) the creation of microplastic-sediment aggregates forming denser structures, that settle down trapping microplastics in sediments; ii) the development of a clay sediment cap that hinders the rise of microplastics to the surface. Reducing the risk of underestimation of microplastic content in mud-rich samples can be accomplished by applying a procedure that involves placing the samples with the Sodium Polytungstate solution on a stirring plate while progressively lowering the rotation velocity. Using this method, cohesive sediments lose their ability to trap microplastics while aggregating, consequently reducing their ability to drag microplastics to the bottom. This facilitated microplastics to reach the liquid surface, thereby enabling an efficient retrieval even in mud-rich samples.