Grafting of Lactic Acid and ε-Caprolactone onto Alpha-Cellulose and Sugarcane Bagasse Cellulose: Evaluation of Mechanical Properties in Polylactic Acid Composites.

In this paper, we present the synthesis of composite materials comprised of α-cellulose and sugarcane bagasse cellulose fibers grafted with lactic acid and ε-caprolactone. These fibers were incorporated as reinforcements into a PLA matrix by extrusion, producing composite materials with improved mechanical properties. The grafting of lactic acid and ε-caprolactone onto the fibers was confirmed by FTIR spectroscopy, demonstrating the chemical modification of the fibers. The morphology of the fibers and composites was analyzed through scanning electron microscopy (SEM), showing that the fibers are encapsulated within the polymeric matrix. This suggests good PLA-fiber interaction for the 90 PLA/10 α-Cel, 90 PLA/10 LAC-g-α-Cel, and 90 PLA/10 ε-CL-g-α-Cel composite materials. The obtained composite materials were tested under tensile loading. Incorporating 10 wt% of LAC-g-FBA-Cel and α-Cel-g-FBA-Cel grafted fibers into the PLA matrix improved the tensile modulus by 28% and 12%, respectively, compared with PLA. The maximum tensile strength values obtained were for composite materials with 10 wt% PLA/α-Cel, LAC-g-α-Cel, and FBA-Cel with 23, 27, and 37% concerning PLA. DSC thermal studies showed a reduction in the glass transition temperature in the composites with grafted fibers. The results suggest better interfacial adhesion between the PLA matrix and both grafted and non-grafted α-cellulose fibers, which contributes to the observed improvements in the mechanical and thermal properties of the composite materials. The results demonstrate that the composites can be produced through extrusion. Once the optimal concentration has been determined, α-cellulose or sugarcane bagasse grafted with lactic acid and ε-caprolactone can be incorporated into the PLA matrix, exhibiting adjustable properties.