Porous pure SnO nanofibers (NFs) and LaO nanoparticles (NPs)-embedded porous SnO NFs were successfully synthesized via electrospinning followed by calcination. These materials were systematically evaluated as gas-sensing elements in metal-oxide-semiconductor (MOS) sensors. The LaO NPs embedded in porous SnO NFs demonstrated superior gas-sensing performance compared to pure SnO NFs. Specifically, the incorporation of LaO resulted in a 12-fold enhancement in gas-sensing response towards ethanol, significantly improving both sensitivity and selectivity by tuning the carrier concentration and modifying oxygen deficiencies and chemisorbed oxygen levels. Thus, LaO NPs embedded in SnO NFs present a promising strategy for the development of high-performance ethanol gas sensors.
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http://dx.doi.org/10.3390/s24216839 | DOI Listing |
Sensors (Basel)
October 2024
Department of Semiconductor System Engineering, Sejong University, 209 Neungdong-ro, Gwangjin-gu, Seoul 05006, Republic of Korea.
Porous pure SnO nanofibers (NFs) and LaO nanoparticles (NPs)-embedded porous SnO NFs were successfully synthesized via electrospinning followed by calcination. These materials were systematically evaluated as gas-sensing elements in metal-oxide-semiconductor (MOS) sensors. The LaO NPs embedded in porous SnO NFs demonstrated superior gas-sensing performance compared to pure SnO NFs.
View Article and Find Full Text PDFNanoscale Horiz
November 2024
Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 42988, Republic of Korea.
In the electrochemical CO reduction reaction (CORR), Cu alloy electrocatalysts can control the CORR selectivity by modulating the intermediate binding energy. Here, we report the thermodynamic-based Cu-Sn bimetallic phase control in heterogeneous catalysts for selective CO conversion. Starting from the thermodynamic understanding about Cu-Sn bimetallic compounds, we established the specific processing window for Cu-Sn bimetallic phase control.
View Article and Find Full Text PDFJ Mater Chem A Mater
December 2024
Mesoscale Chemical Systems, MESA+ Institute, University of Twente P. O. Box 217 Enschede 7500AE The Netherlands.
Electrolyzers operate over a range of temperatures; hence, it is crucial to design electrocatalysts that do not compromise the product distribution unless temperature can promote selectivity. This work reports a synthetic approach based on electrospinning to produce NiO:SnO nanofibers (NFs) for selectively reducing CO to formate above room temperature. The NFs comprise compact but disjoined NiO and SnO nanocrystals identified with STEM.
View Article and Find Full Text PDFACS Nano
July 2024
Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea.
Chemiresistive gas sensors based on semiconducting metal oxides typically rely on noble metal catalysts to enhance their sensitivity and selectivity. However, noble metal catalysts have several drawbacks for practical utilization, including their high cost, their propensity for spontaneous agglomeration, and poisoning effects with certain types of gases. As such, in the interest of commercializing the chemiresistive gas sensor technology, we propose an alternative design for a noble-metal-free sensing material through the case study of Co-doped ceria (Co-CeO) catalysts embedded in a SnO matrix.
View Article and Find Full Text PDFSmall
October 2024
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, China.
Constructing a built-in interfacial electric field (BIEF) is an effective approach to enhance the electrocatalysts performance, but it has been rarely demonstrated for electrochemical carbon dioxide reduction reaction (CORR) to date. Herein, for the first time, SnO/LaOCl nanofibers (NFs) with BIEF is created by electrospinning, exhibiting a high Faradaic efficiency (FE) of 100% C product (CO and HCOOH) at -0.9--1.
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