The global rise in electronic waste is alarming, driven by the persistent use of glass, epoxy, and plastic substrates owing to their cost, stability, flexibility, and transparency. This underscores the need for biodegradable alternatives with similar properties. This study shows that leaf-derived lignocellulose scaffolds can stabilize bio-sourced, solution-processed polymers by acting as natural sequestering media. Such reinforced films, even when based on gelatin ( ~ 60°C), can endure processes over 200°C. We demonstrate dip-coated ethyl cellulose films for commercially viable reflow soldered circuitry. The films offer high flexibility, more than 80% transparency, and surface roughness below 5.5 nm. Advanced OPDs and OECTs fabricated on these films perform comparably to those on glass and the low material cost and simple fabrication process yields a minimal carbon footprint of 1.6 kgCO/m. This work thus opens a vista of possibilities for biodegradable polymers heretofore considered unsuitable for making temperature-stable substrates for state-of-the-art electronics applications.
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http://dx.doi.org/10.1126/sciadv.adq3276 | DOI Listing |
J Fungi (Basel)
December 2024
College of Food Sciences & Technology, Shanghai Ocean University, Shanghai 201306, China.
is one of the widely produced edible fungi worldwide. It is rich in γ-aminobutyric acid (GABA), a non-protein amino acid with important physiological functions in humans. To investigate the functions of key genes in the GABA metabolic pathway of , we isolated the monokaryon from the factory-cultivated strain and then sequenced and assembled the genome using the PacBio Sequel and Illumina NovaSeq sequencing platforms.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China; Henan Center for Outstanding Overseas Scientists, Zhengzhou 450001, China; National Key Laboratory of Biobased Transportation Fuel Technology, China. Electronic address:
Renewable materials derived from lignocellulose are promising materials for different practical applications, including biomedical, food, and agricultural fields. However, the poor mechanical performance and wet stability restrict their applications. Herein, we fabricated PVA/lignocellulose/PBAT (PVA/CLM/PBAT) composite with a "sandwich" structure.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, Southwest Forestry University, Kunming 650224, China; Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, Southwest Forestry University, Kunming 650224, China. Electronic address:
Composites derived from plant fibers are promising reinforcing materials for engineering because of their renewable and easily available characteristics. In this study, a simple pretreatment method was developed to fabricate structurally intact bamboo cellulose scaffolds. Water-stable, flexible, impact-resistant, and high damping ratio bamboo-based rubber composites were synthesized using carboxylated styrene-butadiene latex-impregnated 3D bamboo scaffolds.
View Article and Find Full Text PDFACS Sustain Chem Eng
November 2024
The University of Iowa, Iowa City, Iowa 52242-1002, United States.
The separation of lignocellulose into lignin, cellulose, and hemicellulose without significantly altering the chemical structures of these component biopolymers remains a modern chemical challenge. Lignin, in particular, has potential as a highly valuable feedstock material but remains underutilized due to the difficulty of generating lignin with low modification and condensation. This work investigates the lignin-rich solids ("boron lignin") generated from a previously reported boron Lewis acid-mediated lignocellulose separation and concludes that (1) boron Lewis acid extraction removes 80-85% of carbohydrates from the original lignocellulose sample, and (2) the resulting lignin possesses a low condensation level and high similarity to native lignin structure.
View Article and Find Full Text PDFCarbohydr Polym
January 2025
Yunnan Provincial Key Lab of Soil Carbon Sequestration and Pollution Control, Faculty of Environmental Science & Engineering, Kunming University of Science & Technology, Kunming, 650500, China. Electronic address:
The high value-added utilization of agroforestry waste biomass is an urgent requirment. Herein, a feasible approach was provided to obtain biodegradable cellulose fibrous films from agroforestry waste biomass. The cellulose used was extracted from agroforestry waste biomass and then the cellulose fibrous film was obtained by direct electrospinning.
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