Colored radiative thermal management materials (RTMM) not only provide superior thermoregulatory performance but also satisfy aesthetic requirements. However, the complexity of the preparation procedures and constrained color selection have hindered their widespread adoption. Here, we presented a facile one-step anodizing strategy for fabricating colored dual-mode RTMM based on titanium film (Ti) and P(VDF-HFP) with mid-infrared (MIR) emissivities of 0.07 and 0.96, respectively, which allow for on-demand temperature modulation (rise of 28.2 K and drop of 9 K) without energy consumption. Furthermore, demonstrations of a colored radiative warming membrane also validate the effectiveness of anodizing treatment. The colored Ti/nano PE membrane with 10.8 μm thickness enables a temperature rise of 2.3 K on real human skin, which is much higher than that of commercial fabric with 120 μm thickness (0.7 K). This strategy provides insights for the scalable fabrication and application of colored low emissivity materials, contributing to the goal of a sustainable society.
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http://dx.doi.org/10.1021/acs.nanolett.4c04073 | DOI Listing |
Nanoscale
January 2025
The Canter for Photochemical Sciences and Department of Physics, Bowling Green State University, Bowling Green, Ohio 43403, USA.
Laser diodes based on solution-processed semiconductor quantum dots (QDs) present an economical and color-tunable alternative to traditional epitaxial lasers. However, their efficiency is significantly limited by non-radiative Auger recombination, a process that increases lasing thresholds and diminishes device longevity through excessive heat generation. Recent advancements indicate that these limitations can be mitigated by employing spherical quantum wells, or quantum shells (QSs), in place of conventional QDs.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, 130012, P. R. China.
Multiple resonance thermally activated delayed fluorescence (MR-TADF) materials are preferred for their high efficiency and high colour purity in organic light-emitting diodes (OLEDs). However, the design strategies of MR-TADF emitters in the red region are very limited. Herein, we propose a concept for a paradigm shift in orange-red/deep-red MR emitters by linking the outer phenyl groups in a classical MR framework through intramolecular sulfur (S) locks.
View Article and Find Full Text PDFPhotochem Photobiol
December 2024
Instituto de Química, Universidade de São Paulo, São Paulo, SP, Brazil.
Pyranoflavylium cations are synthetic analogues of pyranoanthocyanins, the much more color-stable compounds that are formed spontaneously from grape anthocyanins during the maturation of red wines. In the present work, our studies of the photophysical properties of pyranoanthocyanin analogues are extended to include nine pyranoflavylium cations substituted with one or two bromo and/or iodo heavy atoms. The room temperature fluorescence, 77 K fluorescence and phosphorescence, triplet formation in solution, and sensitized singlet oxygen formation, with excited state acidity suppressed by the addition of trifluoroacetic acid, are compared to those of similar pyranoflavylium cations that do not contain a heavy atom.
View Article and Find Full Text PDFNanophotonics
April 2024
Laser Micro/Nano-Fabrication Laboratory, School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081, China.
Manipulating the thermal emission in the infrared (IR) range significantly impacts both fundamental scientific research and various technological applications, including IR thermal camouflage, information encryption, and radiative cooling. While prior research has put forth numerous materials and structures for these objectives, the significant challenge lies in attaining spatially resolved and dynamically multilevel control over their thermal emissions. In this study, a one-step ultrafast laser writing technique is experimentally demonstrated to achieve position-selective control over thermal emission based on the phase-change material GeSbTe (GST).
View Article and Find Full Text PDFAppl Radiat Isot
December 2024
Jazan University, College of Science, Department of Physical Sciences, Physics Division, P.O. Box 114, 45142, Jazan, Saudi Arabia; Nanotechnology Research Unit, College of Science, Jazan University, P.O. Box. 114, Jazan, 45142, Saudi Arabia. Electronic address:
This study investigates the structural and luminescent properties UV radiation of Tb³⁺-doped K₇CaY₂(B₅O₁₀)₃ (KCYBO) phosphors prepared using a microwave-assisted sol-gel method, with a focus on the impact of Na⁺ co-doping. Tb³⁺ ions were effectively integrated as evidenced by X-ray diffraction (XRD) and Rietveld analysis, without disrupting the crystal structure. Photoluminescence (PL) analysis showed intense green emissions at 542 nm, which are due to the D₄ → F₅ transition in Tb³⁺.
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