Synthesis, structure, and superconductivity of La Sr K Na CuO.

RSC Adv

Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University Beijing 100871 People's Republic of China.

Published: November 2024

AI Article Synopsis

  • Sodium and potassium were introduced into LaSrCuO to create LaSrKNaCuO solid solutions through a solid-state reaction, resulting in distinct crystallization patterns for different compositions.
  • The substitution of four Sr ions by one Na, one K, and two La ions leads to a varying property, specifically the transition temperature (T), which changes with the composition of the solution.
  • As the Na content increases, the transition temperature initially rises from 14.8 K at low Na concentration (x = 0.00) to 33.9 K at x = 0.10, before dropping to 18.5 K at x = 0.175.

Article Abstract

Sodium and potassium have been doped into LaSrCuO to form La Sr K Na CuO solid solutions by a solid-state reaction, which crystallizes in the 4/ space group when 0 ≤ < 0.16 and when 0.16 < ≤ 0.25. With the equivalent replacement of four Sr by one Na, one K and two La, it is very interesting to find that (the definition is presented in the introduction part) of La Sr K Na CuO does not remain constant with an increase in but first increases from 14.8 K for = 0.00 to 33.9 K for = 0.10 and then decreases to 18.5 K for = 0.175.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11538971PMC
http://dx.doi.org/10.1039/d4ra06045hDOI Listing

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