Surface condensation is ubiquitous in applications such as power generation and desalination. Nonwetting surfaces have been studied extensively for their dropwise condensation potential with reports of dramatic improvements relative to the classical Nusselt equation for film-wise condensation that has long served as a reference theoretical on the condensation heat transfer coefficient. However, a theoretical on the possible condensation heat transfer over a given surface is not available. Considering actual surface topographies as fractal surfaces, we present theoretical upper bounds for gravity-driven and jumping droplet condensation modes in a unified manner. Experimental data on steam condensation from this study as well as the literature on dry nonwetting surfaces are compared to the bounds to identify the opportunity gap to the theoretical maximum. Solid-infused surfaces, introduced recently by the authors, are shown to fall in this opportunity space, closer to the upper bound.
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http://dx.doi.org/10.1016/j.isci.2024.111059 | DOI Listing |
Sci Rep
December 2024
Condensed Matter Theory Group, School of Studies in Physics, Jiwaji University, Gwalior, 474 011, India.
This study presents a comprehensive investigation into the intrinsic properties of RNiP (where R = Sm, Eu) filled skutterudite, employing the full-potential linearized augmented plane wave method within density functional theory (DFT) simulations using the WIEN2k framework. Structural, phonon stability, mechanical, electronic, magnetic, transport, thermal, and optical properties are thoroughly explored to provide a holistic understanding of these materials. Initially, the structural stability of SmNiP and EuNiP is rigorously evaluated through ground-state energy calculations obtained from structural optimizations, revealing a preference for a stable ferromagnetic phase over competing antiferromagnetic and non-magnetic phases.
View Article and Find Full Text PDFJ Aerosol Sci
November 2024
National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention, Cincinnati, OH, 45226, United States.
Trace measurement of aerosol chemical composition in workplace atmospheres requires the development of high-throughput aerosol collectors that are compact, hand-portable, and can be operated using personal pumps. We describe the design and characterization of a compact, high flow, Turbulent-mixing Condensation Aerosol-in-Liquid Concentrator (TCALC) that allows direct collection of aerosols as liquid suspensions, for off-line chemical, biological, or microscopy analysis. The TCALC unit, measuring approximately 12 × 16 × 18 cm, operates at an aerosol sample flowrate of up to 10 L min, using rapid mixing of a hot flow saturated with water vapor and a cold aerosol sample flow, thereby promoting condensational growth of aerosol particles.
View Article and Find Full Text PDFGels
November 2024
School of Mechanical and Aerospace Engineering, Gyeongsang National University, Jinju 52828, Republic of Korea.
Adsorption heat pumps (AHPs) have garnered significant attention due to their efficient use of low-grade thermal energy, eco-friendly nature, and cost-effectiveness. However, a significant challenge lies in developing adsorbent materials that can achieve a high uptake capacity, rapid adsorption rates, and efficient reversible release of refrigerants, such as ammonia (NH). Herein, we developed and synthesized a novel salt-embedded covalent organic framework (COF) composite material designed for enhanced NH capture.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
School of Chemical and Biological Engineering, Institute of Engineering Research, College of Engineering, Seoul National University, Seoul 08826, Republic of Korea.
Stable hollow-type microspheres (MSs) have been fabricated using α-synuclein (αS), an amyloidogenic protein, via freeze-induced protein self-assembly. This assembly process involves three steps: rapid freezing to form spherical protein condensates from αS oligomers, frozen annealing to form a crust on the condensate and freeze-drying to create an interior lumen via the three-dimensional (3D) coffee-stain effect. The crust produced during the frozen-annealing step is a β-sheet-mediated protein structure that is presumed to be created at the quasi-liquid layer of the protein-ice interface and thus contributes to the stability of MSs in aqueous solutions at room temperature without any additional surface stabilization.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
Department of Engineering, College of Engineering and Technology, University of Technology and Applied Sciences, Musandam, PC, 811, Oman.
Among the numerous residential appliances, window or split air conditioners are the most prevalent. The hydrochlorofluorocarbon and hydrofluorocarbon refrigerants used in those systems are causing a serious threat to the environment. In this study, R290-hydrofluoroolefin (HFO) mixtures are proposed as replacements for high-GWP substances (R410A and R22) in window air conditioning (WAC) units.
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