Materials with anisotropic emission characteristics have attracted considerable attention for thermal management. Although many dual-mode emitters have been developed for this purpose in the form of textiles, multilayer films, and photonic structures, multiple functionalities are essential for their versatile applications. Herein, a highly stretchable dual-mode emitter with programmable emissivity and air permeability is presented. The emitter comprises a planar GeSbTe (GST) cavity on one side of a perforated elastomer substrate and an infrared-reflecting metal layer on the other side. With a laser-induced phase transition from amorphous to crystalline GST, the emitter exhibits a large emissivity difference of 0.52 between both sides. The dual-mode emitter remains highly stable without mechanical failure after repeated stretching cycles to a strain of 50%. This air-permeable and stretchable emitter can be attached to any curved surface, including the human body. The GST-side emissivity can be programmed into an arbitrary emissivity pattern using a spatially modulated laser beam, ultimately enabling the printing of mutually independent visible and thermal images in a single emitter. This study provides a promising structure for multispectral optical security as well as thermal management.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/acsami.4c15068 | DOI Listing |
ACS Appl Mater Interfaces
November 2024
Department of Materials Science and Engineering, Yonsei University, Seoul 03722, Korea.
Materials with anisotropic emission characteristics have attracted considerable attention for thermal management. Although many dual-mode emitters have been developed for this purpose in the form of textiles, multilayer films, and photonic structures, multiple functionalities are essential for their versatile applications. Herein, a highly stretchable dual-mode emitter with programmable emissivity and air permeability is presented.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
April 2024
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China.
A general approach to constructing room temperature phosphorescence (RTP) materials involves the incorporation of a phosphorescent emitter into a rigid host or polymers with high glass transition temperature. However, these materials often suffer from poor processability and suboptimal mechanical properties, limiting their practical applications. In this work, we developed benzothiadiazole-based dialkene (BTD-HEA), a multifunctional phosphorescent emitter with a remarkable yield of intersystem crossing (Φ, 99.
View Article and Find Full Text PDFAcc Chem Res
March 2024
Organic Chemistry Division, National Chemical Laboratory (CSIR-NCL), Dr. Homi Bhabha Road, Pune-411008, India.
ConspectusThe invention of solvent-free organic liquids (SOLs) was serendipitous. However, the curiosity-driven research in the later stage delivered new soft materials with exciting optical, and optoelectronic properties along with appealing physical characteristics suitable for the futuristic applications. A slight change in the molecular design resulted in a drastic change in the physical state of molecules demonstrating monomer-like features in the bulk.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2023
Organic Chemistry Division, National Chemical Laboratory (CSIR-NCL), Dr. Homi Bhabha Road, Pune, 411008, India.
The high demand for light-emitting and display devices made luminescent organic materials as attractive candidates. Solvent-free organic liquids are one of the promising emitters among them due to the salient features. However, the inherent limitations of forming sticky and noncurable surfaces must be addressed to become an alternate emitter for large-area device applications.
View Article and Find Full Text PDFPNAS Nexus
June 2023
Thomas Lord Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC 27708, USA.
For centuries, people have put effort to improve the thermal performance of clothing to adapt to varying temperatures. However, most clothing we wear today only offers a single-mode insulation. The adoption of active thermal management devices, such as resistive heaters, Peltier coolers, and water recirculation, is limited by their excessive energy consumption and form factor for long-term, continuous, and personalized thermal comfort.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!