In this study, a MoO@TiO composite core-shell material was developed to remove Rhodamine B (RhB) dye through synergistic adsorption and photocatalytic degradation. n-n heterostructures were formed by coupling n-type semiconductors to enhance the efficiency of photocarrier separation and photocatalytic performance. MoO, which possesses strong adsorption capacity, was primarily used as a dye adsorbent. Additionally, the formation of an n-n heterojunction with TiO enabled MoO to expand the photocorresponding range of TiO, leading to the generation of superoxide (O) and hydroxyl (OH) free radicals for dye degradation. The experimental results demonstrate that the MoO@TiO core-shell composite exhibits excellent performance for RhB dye removal, with adsorption and degradation rates reaching 35.7 and 70.3%, respectively, even at low catalyst concentrations. This approach offers new insights into the development of MoO core-shell photocatalysts.
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http://dx.doi.org/10.1021/acs.langmuir.4c03333 | DOI Listing |
J Mater Chem B
January 2025
Department of Forensic Science, School for Bio Engineering and Bio Sciences, Lovely Professional University, Phagwara, Punjab, India.
The development of pH-directed nanoparticles for tumor targeting represents a significant advancement in cancer biology and therapeutic strategies. These innovative materials have the ability to interact with the unique acidic microenvironment of tumors. They enhance drug delivery, increase therapeutic efficacy, and reduce systemic toxicity.
View Article and Find Full Text PDFThis study investigates (EIG) in a nanohybrid configuration involving a semiconductor quantum dot (SQD) and a core-shell bimetallic nanoparticle coated with graphene. The goal is to optimize interactions between plasmons and excitons. This is achieved by utilizing nanoparticles covered with graphene, which enhances control over surface plasmons.
View Article and Find Full Text PDFNanomicro Lett
January 2025
Energy and Environmental Division, Korea Institute of Ceramic Engineering and Technology, Jinju, Gyeongnam, 52851, Republic of Korea.
All-solid-state batteries (ASSBs) are pursued due to their potential for better safety and high energy density. However, the energy density of the cathode for ASSBs does not seem to be satisfactory due to the low utilization of active materials (AMs) at high loading. With small amount of solid electrolyte (SE) powder in the cathode, poor electrochemical performance is often observed due to contact loss and non-homogeneous distribution of AMs and SEs, leading to high tortuosity and limitation of lithium and electron transport pathways.
View Article and Find Full Text PDFSmall
January 2025
INM - Leibniz Institute for New Materials, Saarland University, Campus D2 2, 66123, Saarbrücken, Germany.
Engineered living materials (ELMs) made of bacteria in hydrogels have shown considerable promise for therapeutic applications through controlled and sustained release of complex biopharmaceuticals at low costs and with reduced wastage. While most therapeutic ELMs use E. coli due to its large genetic toolbox, most live biotherapeutic bacteria in development are lactic acid bacteria due to native health benefits they offer.
View Article and Find Full Text PDFAnal Chem
January 2025
School of Metallurgy, Northeastern University, Shenyang 110819, China.
Sensitive H sensors play key roles in the large-scale and safe applications of H. In this study, we developed novel ternary Pd-loaded SnO@WO core-shell structures by hydrothermal and reduction methods. The compositions of the optimized ternary core-shell structures (Pd-SW-2) are prepared on the basis of the optimal binary core-shell structures (SW-X) according to the sensing performances to H.
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