Degradation of Rhodamine B by Visible Light Driven MoO@TiO Core-Shell Photocatalyst.

Langmuir

Heilongjiang Provincial Key Laboratory of Oilfield Applied Chemistry and Technology, School of Chemical Engineering, Daqing Normal University, Daqing 163712, P. R. China.

Published: November 2024

In this study, a MoO@TiO composite core-shell material was developed to remove Rhodamine B (RhB) dye through synergistic adsorption and photocatalytic degradation. n-n heterostructures were formed by coupling n-type semiconductors to enhance the efficiency of photocarrier separation and photocatalytic performance. MoO, which possesses strong adsorption capacity, was primarily used as a dye adsorbent. Additionally, the formation of an n-n heterojunction with TiO enabled MoO to expand the photocorresponding range of TiO, leading to the generation of superoxide (O) and hydroxyl (OH) free radicals for dye degradation. The experimental results demonstrate that the MoO@TiO core-shell composite exhibits excellent performance for RhB dye removal, with adsorption and degradation rates reaching 35.7 and 70.3%, respectively, even at low catalyst concentrations. This approach offers new insights into the development of MoO core-shell photocatalysts.

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http://dx.doi.org/10.1021/acs.langmuir.4c03333DOI Listing

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