Experimental Realization of Fluoroborophene.

Borophene, an anisotropic metallic Dirac material exhibits superlative physical and chemical properties. While the lack of bandgap restricts its electronic chip applications, insufficient charge carrier density and electrochemical/catalytically active sites, restricts its energy storage and catalysis applications. Fluorination of borophene can induce bandgap and yield local electron injection within its crystallographic lattice. Herein, a facile synthesis of fluoroborophene with tunable fluorine content through potassium fluoride-assisted solvothermal-sonochemical combinatorial approach is reported. Fluoroborophene monolayers with lateral dimension 50 nm-5 µm are synthesized having controlled fluorine content (12-35%). Fluoroborophene exhibits inter-twinned crystallographic structure, with fluorination-tunable visible-range bandgap ≈1.5-2.5 eV, and density functional theory calculations also corroborate it. Fluoroborophene is explored for electrocatalytic oxygen evolution reaction in an alkaline medium and bestow a good stability. Tunable bandgap, electrophilicity and molecular anchoring capability of fluoroborophene will open opportunities for novel electronic/optoelectronic/spintronic chips, energy storage devices, and in numerous catalytic applications.