The removal of emerging contaminants (ECs) from drinking water is a current challenge of global concern. Graphene-based sorbents are attracting increasing interest in this field owing to the chemical versatility of graphene-based materials, their commercial availability and processability in various 3D structures. Herein, for the first time, graphene aerogels (GAs) are reported based on the synergy of graphene oxide (GO) and graphene nanoplatelets (GNPs) derived from waste tire and their use as a sorbent for a mixture of ECs in tap water. Reduction of GO up to 52.1% (O/C = 0.092) was demonstrated through X-ray photoelectron spectroscopy, whereas no changes in the GNP structure during aerogel synthesis were demonstrated with comprehensive spectroscopic and microscopic characterisation. Adsorption of a selection of ECs in a mixture from tap water was tested under flow conditions by inserting the aerogels into filtration cartridges and filtering tap water spiked with the mixture of ECs. Remarkably, the GO + GNP aerogel showed an increase in adsorption capacity of about 2.3 times that of the rGO aerogel owing to the higher obtained surface area, 27 instead of 16 m g, and the resultant more-reduced structure.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11519773 | PMC |
http://dx.doi.org/10.1039/d4ra05658b | DOI Listing |
Dalton Trans
January 2025
Karlsruhe Institute of Technology (KIT), Institute for Inorganic Chemistry, Engesserstrasse 15, 76131 Karlsruhe, Germany.
(Eu[PTC])(Eu[TREN-1,2-HOPO]) inorganic-organic hybrid nanoparticles (IOH-NPs) contain Eu, tris[(1-hydroxy-2-oxo-1,2-dihydropyridine-6-carboxamido)ethyl]amine (TREN-1,2-HOPO) and perylene-3,4,9,10-tetracarboxylate (PTC). The IOH-NPs are prepared in water and exhibit a rod-type shape, with a length of 60 nm and a diameter of 5 nm. Particle size and chemical composition are examined by different methods (SEM, DLS, FT-IR, TG, C/H/N analysis).
View Article and Find Full Text PDFLangmuir
January 2025
Materials Science and Technology Division, CSIR─National Institute for Interdisciplinary Science and Technology, Pappanamcode, Thiruvananthapuram 695019, Kerala, India.
Mercury contamination of the environment is extremely hazardous to human health because of its significant toxicity, especially in water. Biomass-derived fluorophores such as carbon dots (CDs) have emerged as eco-friendly and cost-effective alternative sensors that provide comparable efficacy while mitigating the environmental and economic drawbacks of conventional methods. In this work, we report the fabrication of a selective fluorescence-enhancing sensor based on sulfur-doped carbon dots (SCDs) using waste bamboo-derived cellulose and sodium thiosulfate as the soft base dopant, which actively complexes with mercury ions for detection.
View Article and Find Full Text PDFEpidemiol Infect
January 2025
Health Protection Operations, South West, UK Health Security Agency, Bristol, UK.
In September 2023, the UK Health Security Agency's (UKHSA) South West Health Protection Team received notification of patients with perichondritis. All five cases had attended the same cosmetic piercing studio and a multi-disciplinary outbreak control investigation was subsequently initiated. An additional five cases attending the same studio were found.
View Article and Find Full Text PDFSci Rep
January 2025
Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, Fukuoka, 816-8580, Japan.
This study aimed to evaluate the effects of plasma treated metal contaminated water, used for irrigation, on plant growth. Zinc (Zn) is a commonly used metal that can enter the environment through industrial processes. It may be released as particles into the atmosphere or discharged as wastewater into waterways or the ground.
View Article and Find Full Text PDFAnal Chim Acta
January 2025
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY, 13902, USA; Materials Engineering and Science Program, State University of New York at Binghamton, Binghamton, NY, 13902, USA. Electronic address:
Background: Pesticides are widely used in agriculture to control pests and enhance crop yields. However, post-harvest, there are growing concerns about the potential health risks posed by pesticide residues on produce surfaces. Analyzing these residues is challenging due to their typically low concentrations and the potential interference from the complex matrix of the produce's surface.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!