The two-dimensional electron gas (2DEG) at the LaAlO[Formula: see text]/SrTiO[Formula: see text] (LAO/STO) interface exhibits gate-tunable superconductivity with a dome-like shape of critical temperature as a function of electron concentration. This behavior has not been unambiguously explained yet. Here, we develop a microscopic model based on the Schrödinger-Poisson approach to determine the electronic structure of the LAO/STO 2DEG, which we then apply to study the principal characteristics of the superconducting phase within the real-space pairing mean-field approach. For the electron concentrations reported in the experiment, we successfully reproduce the dome-like shape of the superconducting gap. According to our analysis such behavior results from the interplay between the Fermi surface topology and the gap symmetry, with the dominant extended s-wave contribution. Similarly as in the experimental report, we observe a bifurcation effect in the superconducting gap dependence on the electron density when the 2DEG is electrostatically doped either with the top gate or the bottom gate. Our findings explains the dome-shaped phase diagram of the considered heterostucture with good agreement with the experimental data which, in turn, strongly suggest the appearance of the extended s-wave symmetry of the gap in 2DEG at the LAO/STO interface.
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http://dx.doi.org/10.1038/s41598-024-77460-0 | DOI Listing |
Sci Rep
January 2025
Walter Schottky Institute, Technical University of Munich, 85748, Garching, Germany.
We investigate the growth of amorphous MoSi thin films using magnetron co-sputtering and optimize the growth conditions with respect to crystal structure and superconducting properties (e.g., critical temperature [Formula: see text]).
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Shaanxi Province Key Laboratory of Advanced Functional Materials and Mesoscopic Physics, School of Physics, Xi'an Jiaotong University, 710049, Xi'an, Shaanxi, P. R. China.
Exploration of new superconducting or superhard transition-metal borides has attracted extensive interest in the past few decades. In this study, we conducted comprehensive theoretical investigations in the scandium-boron binary system by employing a structural search method based upon first-principles density functional theory. Among the six predicted superconducting scandium-borides, ScB (3̄) has the highest superconducting transition temperature = 12.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics, University of Basel, Klingelbergstrasse 82, 4056 Basel, Switzerland.
High-precision molecular manipulation techniques are used to control the distance between radical molecules on superconductors. Our results show that the molecules can host single electrons with a spin 1/2. By changing the distance between tip and sample, a quantum phase transition from the singlet to doublet ground state can be induced.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
School of Physics and Information Technology, Shaanxi Normal University, Xi'an 710062, China.
During the preparation of single-domain (S-D) REBaCuO (RE-123) superconducting bulks, the seed crystals can serve as templates for crystal growth, guiding the newly formed crystals to grow in a specific direction, thereby ensuring the consistency of the crystal orientation within the sample. However, the infiltration temperature is typically restricted to approximately 1050 °C when employing NdBaCuO (Nd-123) crystal seeds in the traditional top-seeded infiltration growth (TSIG) technique for producing single-domain Y-123 bulk superconductors. In the present study, to overcome the temperature limitations of the heat treatment process, the optimized YO +011 IG (011 refers to BaCuO powder) method was employed to fabricate a group of single-domain Y-123 bulks with a high-temperature infiltration (1000-1300 °C).
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States.
A recent article ( 2024, 146, 7506-7514) details a pressure-temperature (-) phase diagram for the Ruddlesden-Popper bilayer nickelate LaNiO (LNO-2222) using synchrotron X-ray diffraction. This study identifies a phase transition from (#63) to (#69) within the temperature range of 104-120 K under initial pressure and attributes the 4/ (#139) space group to the structure responsible for the superconductivity of LNO-2222. Herein, we examine the temperature-dependent structural evolution of LNO-2222 single crystals at ambient pressure.
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