When the Study of the Post-Synthetic Modification Method on a 1D Spin Crossover Coordination Polymer Highlights its Catalytic Activity.

We are interested in studying the catalytic activity of the spin crossover (SCO) complex ([Fe(NHtrz)](NO)). In this work, we demonstrate that, by adapting the experimental conditions, we can switch from a quantitative post-synthetic modification (PSM) reaction to the use of this complex as a catalyst for the formation of imine from 4-amino-1,2,4-triazole. During the catalytic reaction, the iron complex undergoes two different PSM reactions: the first is the action of the aldehyde on the NH groups present on the complex, whereas the second PSM reaction occurs between the imine complex and aminotriazole, leading back to the starting complex. These two PSM reactions are at least partially involved in the catalytic mechanism. Furthermore, the combination of these two PSM reactions enables us to modulate the particle size and shape of the final amine complex without altering its excellent SCO properties. This result is of interest in the field of heterogeneous catalysis, where particle size has a strong influence on the catalytic activity, and for the proper integration in devices for different applications.