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X-Type Ligands Effect on the Operational Stability of Heavy-Metal-Free Quantum Dot Light-Emitting Diodes. | LitMetric

X-Type Ligands Effect on the Operational Stability of Heavy-Metal-Free Quantum Dot Light-Emitting Diodes.

Nano Lett

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China.

Published: November 2024

AI Article Synopsis

  • ZnSeTe quantum dots are promising for creating heavy-metal-free LEDs that meet blue light standards.
  • Advances in core-shell engineering have greatly improved the external quantum efficiency of these QD-LEDs.
  • This study investigates how ligand density and composition affect the stability of the materials and devices, finding that replacing organic ligands with inorganic ones enhances their overall stability.

Article Abstract

ZnSeTe quantum dots (QDs) offer an efficient avenue for realizing heavy-metal-free light-emitting diodes (LEDs) that meet the Rec.2100 blue standard. Synthetic core-shell engineering has enabled big advances in the external quantum efficiency (EQE) of ZnSeTe QD-LEDs. However, the mechanisms behind the degradation of the operational stability of ZnSeTe QD-LEDs remain relatively unexplored. In this study, we explore the impact of ligand density and composition on both material and device stability. We developed a solid-film ligand exchange utilizing an inorganic X-type ligand (zinc chloride), revealing that the substitution of inorganic ligands for organic counterparts significantly influences the stability of both materials and devices.

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Source
http://dx.doi.org/10.1021/acs.nanolett.4c04032DOI Listing

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