Anaerobic digestion of fruit and vegetable waste (FVW) offers an environmentally friendly alternative for waste disposal, converting it into methane for energy recovery. Typically, FVW digestion is conducted in a continuously stirred tank reactor (CSTR) due to its ease of use and stability with solid concentrations between 5 and 10%. However, CSTRs are limited to organic loading rates (OLRs) of about 3 kg COD/m.day, resulting in large reactor volumes, low methane productivity, and costly wet digestate handling. This work introduces a novel method for methane production from FVW using a high-rate reactor system. The proposed approach involves grinding, centrifuging, and/or pressing the FVW to separate it into liquid and solid phases. The liquid phase is then digested in an up-flow anaerobic sludge blanket (UASB) reactor, while the solid phase undergoes digestion in a dry methanization reactor. A model incorporating all biological reactors was implemented in the Anaerobic Digestion Model 1 (ADM1) to provide a theoretical basis for the experimental development of this system. The current simulation scenarios offer initial references for operating the experimental system, which will, in turn, generate data for further model refinement. For instance, constrained liquid-gas mass transfer was considered for dry fermentation, with additional potential biochemical kinetic limitations to be incorporated following on experimental evidence. The success of this system could enable energy recovery in 72 Central Wholesale Markets across Brazil, offering a critical tool for planning, operating, and optimizing such systems.
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http://dx.doi.org/10.1007/s11356-024-35328-w | DOI Listing |
J Environ Manage
January 2025
School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083, China.
The cultivation of edible mushrooms plays a significant role in revitalizing numerous rural regions in China. However, this process generates a large amount of spent mushroom substrate (SMS). Traditional methods for handling SMS, such as random stacking and incineration, lead to resource waste and environmental pollution.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Martin-Luther-Universitat Halle-Wittenberg, Department of Chemistry, Kurt-Mothes-Str. 2, 06120, Halle, GERMANY.
A pronounced nucleophilicity in combination with a distinct redox non-innocence is a unique feature of a coordinated ligand, which in the current case, leads to unprecedented carbon-centered reactivity patterns: A carbodiphosphorane-based (CDP) pincer-type rhodium complex allows to cleave two C-Cl-bonds of geminal dichlorides via two consecutive SN2-type oxidative additions resulting in the formation of a stabilized carbene fragment. In the presence of a suitable reductant the carbene fragment can even be converted into olefines or hydrodehalogenation products in a catalytic reaction. The developed method can also be used to convert chlorofluorocarbons (CFCs) such as CH2ClF to fluoromethane and methane.
View Article and Find Full Text PDFEnviron Res
January 2025
School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China. Electronic address:
The pressing necessity to mitigate climate change and decrease greenhouse gas emissions has driven the advancement of heterostructure-based photocatalysts for effective CO₂ reduction. This study introduces a novel heterojunction photocatalyst formed by integrating potassium-doped polymeric carbon nitride (KPCN) with metallic Zn₃N₂, synthesized via a microwave-assisted molten salt method. The resulting Schottky contact effectively suppresses the reverse diffusion of electrons, achieving spatial separation of photogenerated charges and prolonging their lifetime, which significantly enhances photocatalytic activity and efficiency.
View Article and Find Full Text PDFSci Total Environ
January 2025
Program of Sustainability in Biosystems, Institute of Agrifood Research and Technology (IRTA), Caldes de Montbui, Barcelona, Spain. Electronic address:
Paddy fields are a major anthropogenic source of global methane (CH) emissions, a powerful greenhouse gas (GHG). This study aimed at gaining insights of different organic and inorganic conductive materials (CMs) - biochar, fungal melanin, and magnetite - to mitigate CH emissions, and on their influence on key microbial populations, mimicking the postharvest season throughout the degradation of rice straw in microcosms under anaerobic conditions encompassing postharvest paddy rice soils from the Ebro Delta, Spain. Results showed that fungal melanin was the most effective CM, significantly reducing CH emissions by 29 %, while biochar amendment also reduced emissions by 10 %.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Materials, China Academy of Engineering Physics, Jiangyou 621908, China.
Solar-driven dry reforming of methane (DRM) offers a milder, more cost-effective, and promising environmentally friendly pathway compared to traditional thermal catalytic DRM. Numerous studies have extensively investigated inexpensive Ni-based catalysts for application in solar-driven DRM. However, these catalysts often suffer from activity loss due to carbon accumulation.
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