The demand for renewable energy sources has become more urgent due to climate change and environmental pollution. The oxygen evolution reaction (OER) plays a crucial role in green energy sources. This article primarily explores the potential of using non-noble metals, such as transition and rare earth metals, to enhance the efficiency of the OER process. Due to their cost-effectiveness and unique electronic structure, these non-noble metals could be a game-changer in the field. 'Doping,' which is the process of adding a small amount of impurity to a material to alter its properties, and 'synergistic effects,' which refer to the combined effect of two or more elements that is greater than the sum of their individual effects, are two key concepts in this field. Transition and rare earth metals can reduce the overpotential, a measure of the excess potential required to drive a reaction, thus enhancing the OER process by engineering the electronic and surface molecular structure. This article summarizes the roles of various non-noble metals in the OER process and highlights opportunities for researchers to propose innovative ways to optimize the OER process.
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http://dx.doi.org/10.1002/tcr.202400151 | DOI Listing |
ChemSusChem
January 2025
Sun Yat-Sen University, School of Materials Science and Engineering, No. 135, Xingang Xi Road, China, 510006, Guangzhou, CHINA.
Sluggish oxygen evolution reaction (OER) is a crucial part of water splitting and solar fuel generation, which limits their utilization. Ni3S2 is a promising OER catalyst, in which surface reconstruction is an important step to improve performance. In this study, DFT calculations were employed to investigate the effect of surface reconstruction on (001), (110), and (101) surfaces of Ni3S2 in alkaline OER.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Department of Chemistry and Biochemistry, San Francisco State University, San Francisco, California 94132, USA.
The electrochemical oxidation of alcohol molecules has gained significance as a key anode reaction, offering an alternative to the oxygen evolution reaction (OER) for hydrogen (H) production and carbon dioxide (CO) reduction. The (photo)electrochemical oxidation of benzyl alcohol and its derivatives serves as an important model system, not only because benzyl alcohol oxidation is a critical industrial process, but also because it offers valuable insights into electrocatalytic biomass conversion. Tailoring this reaction through electrochemical and photoelectrochemical methods using heterogeneous noble and transition metal electrocatalysts presents a green approach and the potential for uncovering new reaction mechanisms.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004 PR China.
Interface engineering and electronic modulation enable precise tuning of the electronic structure, thereby maximizing the efficacy of active sites and significantly enhancing the activity and stability of the electrocatalyst. Herein, a hybrid material composed of Ni-modified CoS nanoparticles ((Co, Ni)S) encapsulated within an N, S co-doped carbon matrix (SNC) and anchored onto S-doped carbonized wood fibers (SCWF) is synthesized using a straightforward simultaneous carbonization and sulfidation approach. Density functional theory (DFT) calculations reveal that the highly electronegative Ni element promotes electron cloud migration from Co to Ni, shifting the d-band center of Co closer to the Fermi level.
View Article and Find Full Text PDFDalton Trans
January 2025
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060, P. R. China.
Efficient separation of photogenerated charge carriers is essential for maximizing the photocatalytic efficiency of semiconductor materials in oxygen evolution reactions (OER). This study presents a novel trimetallic photocatalyst, MIL-100(Fe)/TiO/CoO, synthesized through a facile microwave-assisted hydrothermal method followed by atomic layer deposition (ALD). The porous MIL-100(Fe) serves as a support for the sequential deposition of TiO and CoO layers ALD, which enhances electron-hole pair separation and minimizes their recombination.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
College of Chemistry and Materials Science, Sichuan Normal University, Chengdu 610066, PR China. Electronic address:
The reasonable design of an economical and robust bifunctional electrocatalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is both essential but challenging. Herein, we synthesized a multi-interfacial NiP/WS/CoWO@C hybrid electrocatalyst devived from the heterometallic clusters [Co(TC4A)(WO)Cl][HPWO], in which NiP was incorporated into WS/CoWO@C nanosheets via interfacial interactions by in situ phosphorization processes. Theoretical calculations revealed that moderate electron transfer from CoWO and NiP to WS induced by the multi-heterojunction significantly regulate the binding energies of the reactive intermediates, thus enhacing its intrinsic activity.
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