The purpose of this study is to investigate the effects of toolpath patterns, geometry types, and layering effects on the mechanical properties of parts manufactured by direct energy deposition (DED) additive manufacturing using data analysis and machine learning methods. A total of twelve case studies were conducted, involving four distinct geometries, each paired with three different toolpath patterns based on finite element method (FEM) simulations. These simulations focused on residual stresses, strains, and maximum principal stresses at various nodes. A comprehensive analysis was performed using a linear mixed-effects (LME) model, principal component analysis (PCA), and self-organizing map (SOM) clustering. The LME model quantified the contributions of geometry, toolpath, and layer number to mechanical properties, while PCA identified key variables with high variance. SOM clustering was used to classify the data, revealing patterns related to stress and strain distributions across different geometries and toolpaths. In conclusion, LME, PCA, and SOM offer valuable insights into the final mechanical properties of DED-fabricated parts.
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http://dx.doi.org/10.3390/ma17205127 | DOI Listing |
J Am Chem Soc
January 2025
Department of Chemistry, BioInspired Institute, Syracuse University, Syracuse, New York 13244, United States.
Understanding structure-mechanical activity relationships (SMARs) in polymer mechanochemistry is essential for the rational design of mechanophores with desired properties, yet SMARs in noncovalent mechanical transformations remain relatively underexplored. In this study, we designed a subset of diarylethene mechanophores based on a lever-arm hypothesis and systematically investigated their mechanical activity toward a noncovalent-yet-chemical conversion of atropisomer stereochemistry. Results from Density functional theory (DFT) calculations, single-molecule force spectroscopy (SMFS) measurements, and ultrasonication experiments collectively support the lever-arm hypothesis and confirm the exceptional sensitivity of chemo-mechanical coupling in these atropisomers.
View Article and Find Full Text PDFPLoS One
January 2025
The Henry M. Jackson Foundation for the Advancement of Military Medicine, Inc., Bethesda, Maryland, United States of America.
The extrusion bioprinting of collagen material has many applications relevant to tissue engineering and regenerative medicine. Freeform Reversible Embedding of Suspended Hydrogels (FRESH) technology is capable of 3D printing collagen material with the specifications and details needed for precise tissue guidance, a crucial requirement for effective tissue repair. While FRESH has shown repeated success and reliability for extrusion printing, the mechanical properties of completed collagen prints can be improved further by post-print crosslinking methodologies.
View Article and Find Full Text PDFPlant Cell
January 2025
Institute of Science and Technology Austria, Am Campus 1, 3400 Klosterneuburg, Austria.
Super-resolution methods provide far better spatial resolution than the optical diffraction limit of about half the wavelength of light (∼200-300 nm). Nevertheless, they have yet to attain widespread use in plants, largely due to plants' challenging optical properties. Expansion microscopy improves effective resolution by isotropically increasing the physical distances between sample structures while preserving relative spatial arrangements and clearing the sample.
View Article and Find Full Text PDFExcavation of underground engineering structures involving deeply buried water-rich soft rocks is generally carried out using the artificial freezing method. A series of undrained uniaxial and triaxial shear and creep tests were conducted on soft rocks under different confining pressures (0, 0.2, 0.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Faculty of Engineering and Natural Sciences, Sabanci University, Istanbul, 34956, Türkiye.
Skin-like bioelectronics offer a transformative technological frontier, catering to continuous and real-time yet highly imperceptible and socially discreet digital healthcare. The key technological breakthrough enabling these innovations stems from advancements in novel material synthesis, with unparalleled possibilities such as conformability, miniature footprint, and elasticity. However, existing solutions still lack desirable properties like self-adhesivity, breathability, biodegradability, transparency, and fail to offer a streamlined and scalable fabrication process.
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