This study aimed to enhance the performance of dental resin composites (DRCs) by increasing the content of inorganic fillers while addressing potential health risks associated with Bisphenol A (BPA). To achieve this, the BPA-based resin monomer Bis-GMA was replaced with BPA-free Bis-EFMA. The study then explored the impact of varying inorganic filler contents on the physiochemical properties of Bis-EFMA-based bulk-fill dental resin composites (BF-DRCs). Four distinct Bis-EFMA-based BF-DRCs were formulated, each with different inorganic filler contents ranging from 70 wt% to 76 wt%. The study tested the depth of cure (DOC), double-bond conversion (DC), water sorption (WS), solubility (SL), and cytotoxicity of the system. It notably investigated the effects of increasing filler content on mechanical properties through flexural strength (FS), flexural modulus (FM), Vickers microhardness (VHN), and wear resistance, as well as the impact on polymerization shrinkage, including volumetric shrinkage (VS) and shrinkage stress (SS). To assess the commercial application potential of Bis-EFMA-based BF-DRC, the research used the commercially available BF-DRC Filtek Bulk-Fill Posterior (FBF) as a control. The results indicated that a higher filler content did not affect the DOC of Bis-EFMA-based BF-DRCs. Inorganic fillers at higher concentrations significantly enhanced overall mechanical properties while significantly reducing volumetric shrinkage (VS; < 0.05). When the concentration of inorganic fillers in the resin system reached 76 wt%, most of the performance of the Bis-EFMA-based BF-DRC surpassed that of the commercial control FBF, except for FS, FM, and SS. These findings highlight the potential of Bis-EFMA-based BF-DRC as a long-term restorative material for dental applications.
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http://dx.doi.org/10.3390/ma17205040 | DOI Listing |
RSC Adv
January 2025
Department of Electrical Engineering and Electronics, University of Liverpool Brownlow Hill Liverpool L69 3GJ UK
In response to the demand for epoxy-based dielectric substrates with low dielectric loss in high-frequency and high-speed signal transmission applications, this study presents a surface-engineered filler material. Utilizing ball-milling, surface-modified aluminum flakes containing organic (stearic acid) and inorganic (aluminum oxide) coatings are developed. Incorporation of the filler into the epoxy matrix results in a significant increase in dielectric permittivity, by nearly 5 times (from 4.
View Article and Find Full Text PDFSoft Matter
January 2025
Faculty of Science and Letters, Department of Chemistry, Soft Materials Research Laboratory, Istanbul Technical University, Istanbul, Maslak, 34469, Turkey.
A series of anionic poly(acrylamide--sodium acrylate)/poly(ethylene glycol), PAN/PEG, hybrids were conveniently synthesized free radical aqueous polymerization by integrating bentonite, kaolin, mica, graphene and silica, following a simple and eco-friendly crosslinking methodology. A comparative perspective was presented on how integrated nanofillers affect the physicochemical properties of hybrid gels depending on the differences in their structures. Among the five types of nanofillers, bentonite-integrated hybrid gel had the highest water absorbency, while graphene-integrated gel had the lowest.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Department of Conservative Dentistry, University Hospital, Ludwig-Maximilians-University, Goethestr. 70, D-80336 Munich, Germany.
Objective: It is hypothesized that the way nano- and micro-hybrid polymer-based composites are structured and cured impacts the way they respond to aging.
Material And Methods: A polymer-ceramic interpenetrating network composite (Vita Enamic/VE), an industrially polymerized (Brillinat CriosST/BC), and an in situ light-cured composite with discrete inorganic fillers (Admira Fusion5/AF5) were selected. Specimens (308) were either cut from CAD/CAM blocks (VE/BC) or condensed and cured in white polyoxymethylene molds (AF5) and subjected to four different aging conditions ( = 22): (a) 24 h storage in distilled water at 37 °C; (b) 24 h storage in distilled water at 37 °C followed by thermal cycling for 10,000 cycles 5/55 °C (TC); (c) TC followed by storage in a 75% ethanol-water solution; and (d) TC followed by a 3-week demineralization/remineralization cycling.
Nano Lett
January 2025
Department of Forest Biomaterials, North Carolina State University, Raleigh, North Carolina 27607, United States.
Albeit there is widespread application of thermally conductive polymer composites, one challenge is their typical negative temperature dependence on thermal conductivity (TDTC) due to the mismatch in thermal expansion between the polymer and fillers, creating voids at the interfaces. Inspired by the hierarchical structure of snakeskin, where rigid scales and a soft intergap manage expansion, we designed a segregated structure by coating a high-expansion high impact polystyrene (HIPS)/graphite (Gt) composite with a copper alloy. We hypothesize that the Cu alloy restricts the thermal expansion of HIPS/Gt while forming a pseudoconductive network, enhancing TDTC and thermal conductivity (TC).
View Article and Find Full Text PDFJ Mater Chem B
January 2025
Centre for 3D Models of Health and Disease, Division of Surgery and Interventional Science, Faculty of Medical Sciences, University College London, London, UK.
The significance of three-dimensional (3D) bioprinting in the domain of regenerative medicine and tissue engineering is readily apparent. To create a multi-functional bioinspired structure, 3D bioprinting requires high-performance bioinks. Bio-inks refer to substances that encapsulate viable cells and are employed in the printing procedure to construct 3D objects progressive through successive layers.
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