Exploring the relationship between urban, agricultural, and ecological functions is crucial for optimizing the territorial spatial patterns and achieving balanced territorial spatial development. Based on the classification system of "urban-agricultural-ecological" territorial spatial planning and with the help of multi-source data, including land use, population density, nighttime light, road network, precipitation, and county statistical data from 2010 to 2020, we constructed an evaluation index system of territorial space functions at the grid scale in the Poyang Lake Ecological Economic Zone. The coupling coordination levels among territorial space functions was measured using the coupling coordination degree model and spatial autocorrelation analysis. Moreover, the multi-dimensional function conflict identification model was used to diagnose the type and intensity of function conflicts. The results showed that: ① The urban function was mainly improved, accounting for 75.67%. The grids with high function evaluation index were mainly located in the south of the study area, whereas the intensity of urban function improvement in the north was higher than that in the south. Otherwise, the agricultural and ecological functions were mainly reduced, accounting for 77.44 % and 57.66%, respectively, and the majority of grids with a significant decrease were distributed in the south of Poyang Lake. ② From 2010 to 2020, the coupling coordination type was dominated by an imbalance recession, accounting for 53.87% and 49.89 %, respectively. However, the number of grids with crucial imbalance and primary coordination was reduced, and the coupling coordination types tended to change from both ends to the middle. The coupling coordination hot spots were mainly concentrated in the southern plain, whereas the cold spots were mainly distributed in the northern mountainous and hilly areas, both of which showed a reducing trend. However, in the north of Poyang Lake, a small number of hot spots, distributed along the lake area with relatively flat terrain, showed an expanding trend. ③ The intensity of four territorial space function conflicts was mainly moderate or severe. In addition to the slight positive trend of 'urban-agricultural' function conflict, the function conflicts of "urban-ecological", "agricultural-ecological", and "urban-agricultural-ecological" were all aggravated. The grids with aggravating conflicts were mainly distributed in the Ganjiang River and Fuhe River Basin. The major reason for the aggravation was that the urban function increased obviously, whereas the ecological and agricultural functions decreased significantly. In conclusion, in both the coupling coordination types and multi-dimensional conflicts among territorial space functions, significant spatial differences existed; thus, proposing optimization strategies according to local conditions is necessary. Additionally, the protection of ecological and agricultural spaces during each stage of urbanization development must be focused.
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http://dx.doi.org/10.13227/j.hjkx.202311069 | DOI Listing |
Nat Commun
January 2025
School of Pharmacy, Nanjing University of Chinese Medicine, Nanjing, China.
Stereocontrolled construction of tetrasubstituted olefins has been an attractive issue yet remains challenging for synthetic chemists. In this manuscript, alkynyl selenides, when treated with ArBCl, are subject to an exclusive 1,1-carboboration, affording tetrasubstituted alkenes with excellent levels of E-selectivity. Detailed mechanistic studies, supported by DFT calculations, elucidates the role of selenium in this 1,1-addition process.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
Coordinatively unsaturated copper (Cu) has been demonstrated to be effective for electrifying CO reduction into C products by adjusting the coupling of C-C intermediates. Nevertheless, the intuitive impacts of ultralow coordination Cu sites on C products are scarcely elucidated due to the lack of synthetic recipes for Cu with low coordination numbers and its vulnerability to aggregation under reductive potentials. Herein, computational predictions revealed that Cu sites with higher levels of coordinative unsaturation favored the adsorption of C and C intermediates.
View Article and Find Full Text PDFSensors (Basel)
January 2025
College of Resource Environmental and Safety Engineering, University of South China, Hengyang 421001, China.
To solve the issue of inconvenient and dangerous manual operation during the installation and removal of the main pipe plugging plate in the steam generator in nuclear power plants, a ten-degree-of-freedom plugging robot was designed in the present study that includes a collaborative robotic arm coupled with a servo electric cylinder. By establishing a joint coordinate system for the robot model, a D-H parameter model for the plate plugging robot was established, and the forward and inverse kinematics were solved. The volume level approximate convex decomposition algorithm was used to fit the steam generator model with a convex packet, and an experimental simulation platform was constructed.
View Article and Find Full Text PDFSensors (Basel)
January 2025
Peking University Yangtze River Delta Institute of Optoelectronics, Nantong 100871, China.
To improve the performance of Radio Frequency Identification (RFID) multi-label systems, the multi-label network structure needs to be quickly located and optimized. A multi-label location measurement method based on the NLM-Harris algorithm is proposed in this paper. Firstly, multi-label geometric distribution images are obtained through a label image acquisition system of a multi-label semi-physical simulation platform with two vertical Charge-Coupled Device (CCD) cameras, and Gaussian noise is added to the image to simulate thermoelectric interference.
View Article and Find Full Text PDFMolecules
January 2025
N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, 119991 Moscow, Russia.
The interaction of sodium phytate hydrate CHOP·xNa·yHO (phytNa) with Cu(OAc)·HO and 1,10-phenanthroline (phen) led to the anionic tetranuclear complex [Cu(HO)(phen)(phyt)]·2Na·2NH·32HO (), the structure of the latter was determined by X-ray diffraction analysis. The phytate is completely deprotonated; six phosphate fragments (with atoms P1-P6) are characterized by different spatial arrangements relative to the cyclohexane ring (1a5e conformation), which determines two different types of coordination to the complexing agents-P1 and P3, P4, and P6 have monodentate, while P2 and P5 are bidentately bound to Cu cations. The molecular structure of the anion complex is stabilized by a set of strong intramolecular hydrogen bonds involving coordinated water molecules.
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