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Synergetic spin crossover and fluorescence in a mononuclear iron(III) complex. | LitMetric
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Synergetic spin crossover and fluorescence in a mononuclear iron(III) complex.

Zi-Xuan Fan Kai-Ting Lian Pei-Yu Liao Ze-Yu Ruan Zhao-Ping Ni Ming-Liang Tong

Chem Commun (Camb)

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Institute of Green Chemistry and Molecular Engineering, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

Published: November 2024

Two mononuclear iron(III) complexes (XEA)[Fe(azp)]·HO (Hazp = 2,2'-azodiphenol, XEA = 2-fluoroethylammonium and 2-chloroethylammonium) are synthesized, which exhibit the counterion dependence of magnetic and fluorescent properties. The synergetic effect between abrupt spin crossover and fluorescence is observed in an iron(III) complex for the first time.

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 Source
http://dx.doi.org/10.1039/d4cc05036cDOI Listing

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