Porous nanoreactors mimic the structures and functions of cells, providing an adaptable material with multiple functions and effects. These reactors can be nanoscale containers and shuttles or catalytic centres, drawing in reactants for cascading reactions with multishelled designs. The detailed construction of multi-level reactors at the nanometre scale remains a great challenge, but to regulate the reaction pathways within a reactor, designs of great intricacy are required. In this Review, we define the basic structural characteristics of porous nanoreactors, while also discussing the design principles and synthetic chemistry of these structures with respect to their emerging applications in energy storage and heterogeneous catalysis. Finally, we describe the difficulties of the structural optimization of these reactors and propose possible ways to improve porous nanoreactor design for future applications.
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http://dx.doi.org/10.1038/s41570-024-00658-3 | DOI Listing |
Sci Technol Adv Mater
October 2024
Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki, Japan.
Developing electrochemical energy storage and conversion systems, such as capacitors, batteries, and fuel cells is crucial to address rapidly growing global energy demands and environmental concerns for a sustainable society. Significant efforts have been devoted to the structural design and engineering of various electrode materials to improve economic applicability and electrochemical performance. The yolk-shell structures represent a special kind of core-shell morphologies, which show great application potential in energy storage, controlled delivery, adsorption, nanoreactors, sensing, and catalysis.
View Article and Find Full Text PDFLangmuir
November 2024
Engineering Research Center of Ministry of Education for Fine Chemicals, School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China.
Hollow carbon-nitrogen nanoreactors constitute a class of porous materials that have widespread application owing to their large inner cavities, low densities, core-shell interfaces, and enrichment effects. Direct carbonization of precursors is the simplest and most economical method to prepare porous carbon-nitrogen materials; however, this method requires high temperatures, thus yielding nonoxide structures. In this study, CuO-ZnO@CN (CN: carbon-nitrogen layers) is prepared using the two-step heating of zeolitic imidazolium skeleton-8 (ZIF-8) coated with CuO-ZnO precursors.
View Article and Find Full Text PDFTheranostics
October 2024
State Key Laboratory of Bioactive Molecules and Druggability Assessment, Jinan University, Guangzhou 511443, China.
The endogenous immunomodulator adenosine (ADO) was expected to be potentialized as an efficacious mediator to combat psoriasis. However, its efficacy is severely hindered by its poor metabolic stability and insufficient accumulation at the dermatological lesions. In this study, a biomineralized catalytic nanoreactor was delicately customized by encapsulating ADO precursor (adenosine monophosphate, AMP) within the internal porous skeleton of zeolitic imidazolate framework-90, followed by the biomineralization of the AMP catabolic enzyme on the outer layer.
View Article and Find Full Text PDFNat Rev Chem
December 2024
College of Energy Materials and Chemistry, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, China.
Porous nanoreactors mimic the structures and functions of cells, providing an adaptable material with multiple functions and effects. These reactors can be nanoscale containers and shuttles or catalytic centres, drawing in reactants for cascading reactions with multishelled designs. The detailed construction of multi-level reactors at the nanometre scale remains a great challenge, but to regulate the reaction pathways within a reactor, designs of great intricacy are required.
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2024
School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (HUST), Wuhan, 430074, China.
Engineering of hollow particles with tunable internal structures often requires complicated processes and/or invasive cleavage. Halogen-bond driven 3D confined-assembly of block copolymers has shed light on the engineering of polymer organization along with the fabricating of unique nanostructures. Herein, a family of multilevel hollow-structured particles (e.
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