AI Article Synopsis
- Researchers found that carbon dioxide can be inserted into a silicon-nitrogen bond of a specific chemical compound (N-heterocyclic iminosilane) in a way that can be reversed.
- Tests in liquid conditions showed that this insertion process doesn't release or absorb heat, making it thermoneutral, and can go back to its original state.
- In solid form, the carbon dioxide can be stored for a long time, but it only gets released when heated to 133°C.
Article Abstract
The reversible insertion of carbon dioxide into the silicon-nitrogen bond of an N-heterocyclic iminosilane is reported. Solution-phase thermodynamic investigations indicate that this process is thermoneutral and reversible, whereas in the solid-phase CO can be stored for extended periods and is only released upon heating to 133 °C.
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| http://dx.doi.org/10.1039/d4cc04798b | DOI Listing |
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